Synthesis and characterization of ether bridged polymers and their fluorescent, thermal, conductivity, optical and electrochemical properties

被引:12
作者
Kaya, Ismet [1 ]
Temizkan, Kevser [1 ]
Aydin, Aysel [1 ]
机构
[1] Canakkale Onsekiz Mart Univ, Fac Sci & Arts, Dept Chem, Polymer Synth & Anal Lab, TR-17020 Canakkale, Turkey
关键词
Elimination; Ether bridged polymer; Electrochemistry; Fluorescence; ELECTRICAL-CONDUCTIVITY; PHASE-TRANSFER; ELIMINATION; DERIVATIVES; SUBSTITUENT; DEGRADATION; SOLUBILITY; STABILITY; OXIDATION; THIOPHENE;
D O I
10.1016/j.jelechem.2013.09.021
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper describes the synthesis of novel ether bridged polymers containing carbazole units via HBr elimination. Also, these polymers include the ether bridged aliphatic chains at different lengths in their structures. The synthesized polymers were characterized by FT-IR, NMR and UV-Vis spectroscopy, and their thermal stabilities were determined by TGA measurements. Additionally, the oxidation peak potentials of compounds were demonstrated using cyclic voltammetry method. Fluorescence measurements were performed using dimethylformamide solution, and the optimization of concentrations to obtain the maximal emission intensity was also investigated in dimethylformamide solution. The morphologic properties of the polymers were obtained by using scanning electron microscopy at different amplifications. Moreover, the number average molecular weight, weight average molecular weight and polydispersity index values of polymers were determined by size exclusion chromatography technique. As a result, some remarkable properties related to the fluorescence and thermal measurements of the polymers were obtained. Because of the fluorescence and thermal properties of these polymers, they could be used in various application fields, such as fluorescence sensors and space crafts. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:54 / 61
页数:8
相关论文
共 50 条
[41]   Synthesis and electrochemical properties of ferrocene dimers and trimers bridged by an oligothiophene spacer [J].
Muraoka, Hiroki ;
Ogawa, Satoshi .
PURE AND APPLIED CHEMISTRY, 2013, 85 (04) :777-784
[42]   Synthesis, Optical Characterization, and Electrochemical Properties of Isomeric Tetraphenylbenzodifurans Containing Electron Acceptor Groups [J].
Santos-Perez, Javier ;
Crespo-Hernandez, Carlos E. ;
Reichardt, Christian ;
Cabrera, Carlos R. ;
Feliciano-Ramos, Ileana ;
Arroyo-Ramirez, Lisandra ;
Meador, Michael A. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (17) :4157-4168
[43]   Synthesis, Optical and Electrochemical Properties of Arylenevinylene-Based π-Conjugated Polymers with Imidazolium Units in the Main Chain [J].
Toba, Masaya ;
Nakashima, Takuya ;
Kawai, Tsuyoshi .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (08) :1895-1906
[44]   Synthesis, characterization, thermal and optical properties of styrene derivatives having pendant p-substituted benzylic ether groups [J].
Erol, Ibrahim ;
Ozcan, Levent ;
Yurdakal, Sedat .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 114 (01) :377-385
[45]   Cyclometalated Ruthenium, Osmium, and Iridium Complexes Bridged by an NCN-Pyrene-NCN Derivative - Synthesis and Comparison of Optical, Thermal, and Electrochemical Properties [J].
Zych, Dawid ;
Slodek, Aneta ;
Golba, Sylwia ;
Krompiec, Stanislaw .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (14) :1581-1588
[46]   A multifunctional poly(aryl ether) with oligoaniline and fluorene pendants: Synthesis, electrochromic performance, and tunable fluorescent properties [J].
Chao, Danming ;
Yang, Rui ;
Jia, Xiaoteng ;
Liu, Hongtao ;
Wang, Shutao ;
Wang, Ce ;
Berda, Erik B. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (12) :2330-2336
[47]   High temperature stable conjugated polyazomethines containing naphthalene moiety: Synthesis, characterization, optical, electrical and thermal properties [J].
Sengottuvelu, Dineshkumar ;
Athianna, Muthusamy ;
Siddeswaran, Anand .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2021, 246
[48]   Synthesis and characterization of organo-soluble polyamides containing triaryl imidazole pendant and ether linkage moieties: thermal, photophysical, and chemiluminescent properties [J].
Ghaemy, M. ;
Nasab, S. M. Amini .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (12) :2311-2318
[49]   Low potential electrochemical polymerization of diphenyl ether and characterization of its polymers [J].
Xu, Jingkun ;
Wan, Liang ;
Li, Yuzhen ;
Liu, Houting ;
Pu, Shouzhi ;
Shen, Hang .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (24) :5932-5941
[50]   A novel polyphenol: synthesis, characterization and investigation of its thermal and electrochemical properties [J].
Demir, Haci Okkes .
POLYMER JOURNAL, 2012, 44 (07) :699-705