A theoretical study on the ring expansion of NHCs by silanes

被引：42

作者：

Iversen, Kalon J. ^{[1
]}

Wilson, David J. D. ^{[1
]}

Dutton, Jason L. ^{[1
]}

机构：

[1] La Trobe Univ, La Trobe Inst Mol Sci, Dept Chem, Melbourne, Vic, Australia

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 31期

关键词：

N-HETEROCYCLIC CARBENES; ACTIVATION; BOND;

D O I：

10.1039/c3dt51503f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A theoretical study focusing on the ring expansion that occurs in the reaction of N-heterocyclic carbenes with silanes has been carried out. A detailed reaction pathway was determined which indicates that formation of C-H bonds is the crucial factor in the transformation.

引用

页码：11035 / 11038

页数：4

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