A rapid and inexpensive method for 226Ra and 228Ra measurements of high TDS groundwaters

被引:10
作者
El-Shrakawy, A. [1 ,2 ]
Ebaid, Y. Y. [2 ,3 ]
Burnett, W. C. [4 ]
Aldaihan, Soaad K. [5 ]
机构
[1] Atom Energy Author, Natl Ctr Nucl Safety & Radiat Control, Cairo 11762, Egypt
[2] Technol Experts Co, Riyadh 11313, Saudi Arabia
[3] Fayoum Univ, Dept Phys, Fac Sci, Al Fayyum 63514, Egypt
[4] Florida State Univ, Dept Earth Ocean & Atmospher Sci, Tallahassee, FL 32306 USA
[5] King Saud Univ, Dept Biochem, Coll Sci, Riyadh 11495, Saudi Arabia
关键词
Radium; Groundwater; High TDS; Cation exchange; Saudi Arabia; NATURAL-WATERS; ACTINIDE ELEMENTS; RADIUM ISOTOPES; PRECONCENTRATION; SEPARATION; EXTRACTION; URANIUM;
D O I
10.1016/j.apradiso.2013.02.013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of laboratory-scale studies was conducted by preconcentrating Ra-226 from spiked water test samples using Purolite ion-exchange resin to evaluate the adsorption efficiency of the resin under varying conditions. After removing the resin from the columns, it was sealed in gas-tight containers and measured via gamma spectrometry. The Purolite resin showed high radium uptake and retention from natural waters in the presence of high iron and total dissolved solids (TDS). This procedure allowed us to process a large number of high TDS samples at a typical rate of 15 samples/day using three germanium detectors. Quality assurance and method validation have been achieved by analyzing selected groundwater samples, with different Ra-226 activities and high TDS values, and comparing the results to those using alpha spectrometry with a Ba-133 yield tracer. There was very good agreement between the obtained Ra-226 activities by both methods. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:89 / 93
页数:5
相关论文
共 22 条
[1]  
Ayranov M, 2006, CZECH J PHYS, V56, pD219
[2]   High 226Ra and 228Ra activities in Nueces Bay, Texas indicate large submarine saline discharges [J].
Breier, J. A. ;
Edmonds, H. N. .
MARINE CHEMISTRY, 2007, 103 (1-2) :131-145
[3]   Pre-concentration of actinide elements from soils and large volume water samples using extraction chromatography [J].
Burnett, WC ;
Corbett, DR ;
Schultz, M ;
Horwitz, EP ;
Chiarizia, R ;
Dietz, M ;
Thakkar, A ;
Fern, M .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1997, 226 (1-2) :121-127
[4]   DETERMINATION OF RADIUM IN NATURAL-WATERS BY ALPHA LIQUID SCINTILLATION [J].
BURNETT, WC ;
TAI, WC .
ANALYTICAL CHEMISTRY, 1992, 64 (15) :1691-1697
[6]   Determination of 228Ra, 226Ra and 224Ra in natural water via adsorption on MnO2-coated discs [J].
Eikenberg, J ;
Tricca, A ;
Vezzu, G ;
Bajo, S ;
Ruethi, M ;
Surbeck, H .
JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 2001, 54 (01) :109-131
[7]   DETERMINATION OF RADIUM IN WATER BY LIQUID SCINTILLATION-COUNTING AFTER PRECONCENTRATION WITH ION-EXCHANGE RESIN [J].
HIGUCHI, H ;
UESUGI, M ;
SATOH, K ;
OHASHI, N ;
NOGUCHI, M .
ANALYTICAL CHEMISTRY, 1984, 56 (04) :761-763
[8]   SEPARATION AND PRECONCENTRATION OF ACTINIDES FROM ACIDIC MEDIA BY EXTRACTION CHROMATOGRAPHY [J].
HORWITZ, EP ;
CHIARIZIA, R ;
DIETZ, ML ;
DIAMOND, H .
ANALYTICA CHIMICA ACTA, 1993, 281 (02) :361-372
[9]  
Jia G., 2004, J RADIOANAL NUCL CHE, V267, P505
[10]   Ultra-trace determination of 226Ra in thermal waters by high sensitivity quadrupole ICP-mass spectrometry following selective extraction and concentration using radium-specific membrane disks [J].
Joannon, S ;
Pin, C .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2001, 16 (01) :32-37