Highly selective removal of heterocyclic impurities from toluene by nonporous adaptive crystals of perethylated pillar[6]arene

被引：20
|
作者：
Zhu, Weijie [1 ]
Li, Errui [1 ]
Zhou, Jiong [1 ]
Zhou, Yujuan [1 ]
Sheng, Xinru [1 ]
Huang, Feihe [1 ]
机构：
[1] Zhejiang Univ, Ctr Chem High Performance & Novel Mat, Dept Chem, State Key Lab Chem Engn, Hangzhou 310027, Peoples R China
来源：
MATERIALS CHEMISTRY FRONTIERS | 2020年 / 4卷 / 08期
基金：
中国国家自然科学基金;
关键词：
DESORPTION; ADSORPTION; DESULFURIZATION; COMPLEXATION; THIOPHENE; ZEOLITES; FUELS;
D O I：
10.1039/d0qm00334d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The removal of heterocyclic impurities from toluene in the petrochemical industry is necessary but challenging. Herein, we provide a convenient and environmentally friendly adsorptive separation strategy using nonporous adaptive crystals of perethylated pillar[6]arene (EtP6). These crystals show a highly selective preference for heterocyclic compounds, and are capable of selectively adsorbing them from a mixture of toluene and heterocyclic compounds, ultimately improving the purity of toluene from 96.78% to 99.00%. Single crystal structures indicate that the selectivity derives from the differences in the structural stability of the guest-loadedEtP6crystals.
引用
收藏
页码：2325 / 2329
页数：5
相关论文
共 44 条
  • [1] Separation of Monochlorotoluene Isomers by Nonporous Adaptive Crystals of Perethylated Pillar[5]arene and Pillar[6]arene
    Wang, Mengbin
    Zhou, Jiong
    Li, Errui
    Zhou, Yujuan
    Li, Qing
    Huang, Feihe
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (43) : 17102 - 17106
  • [2] Near-perfect separation of alicyclic ketones and alicyclic alcohols by nonporous adaptive crystals of perethylated pillar[5]arene and pillar[6]arene
    Chen, Jingyu
    Wu, Sha
    Wang, Yuhao
    Zhou, Jiong
    CHINESE CHEMICAL LETTERS, 2025, 36 (04)
  • [3] Highly selective separation of toluene and methylcyclohexane based on nonporous adaptive crystals of hybrid[3]arene
    Wei, Shiqi
    Wang, Yuhao
    Zhou, Jiong
    MATERIALS CHEMISTRY FRONTIERS, 2024, 8 (19) : 3150 - 3156
  • [4] Highly selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals
    Liu, Zhongwen
    Li, Ming
    Fang, Shuai
    Shao, Li
    Hua, Bin
    Huang, Feihe
    ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (10) : 2756 - 2761
  • [5] Revealing the mechanism behind the highly selective separation of 1,4-butyrolactone from n-methylpyrrolidone using nonporous adaptive crystals of perethylated pillar[5]arene
    Yin, Minlei
    Yang, Chen
    Tang, Duanlian
    Huang, Shiyin
    Lou, Xiaoyu
    Cui, Rongkai
    Ye, Changshen
    Chen, Jie
    Qiu, Ting
    CHEMICAL ENGINEERING JOURNAL, 2024, 495
  • [6] Perfect Separation of n-Pentane and Iso-pentane by Nonporous Adaptive Crystals of Perethylated Pillar[5]arene
    Chen, Jingyu
    Liang, Xinkai
    Pan, Chunlong
    Liang, Minghao
    Yang, Wenzhi
    Wu, Sha
    Zhu, Haoze
    Zhou, Jiong
    CRYSTAL GROWTH & DESIGN, 2024, 24 (19) : 7749 - 7754
  • [7] Separation of Bromoalkanes Isomers by Nonporous Adaptive Crystals of Leaning Pillar[6]arene
    Wu, Jia-Rui
    Li, Bao
    Yang, Ying-Wei
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (06) : 2251 - 2255
  • [8] Separation of pyrrolidine from tetrahydrofuran by using pillar[6]arene-based nonporous adaptive crystals
    Cao, Jiajun
    Wu, Yitao
    Li, Qi
    Zhu, Weijie
    Wang, Zeju
    Liu, Yang
    Jie, Kecheng
    Zhu, Huangtianzhi
    Huang, Feihe
    CHEMICAL SCIENCE, 2022, 13 (25) : 7536 - 7540
  • [9] Reversible Iodine Capture by Nonporous Pillar[6]arene Crystals
    Jie, Kecheng
    Zhou, Yujuan
    Li, Errui
    Li, Zhengtao
    Zhao, Run
    Huang, Feihe
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (43) : 15320 - 15323
  • [10] Reversible Iodine Capture by Nonporous Pillar[6]arene Crystals
    Huang, Feihe (fhuang@zju.edu.cn), 1600, American Chemical Society (139):
12345