Metal-Cation-Directed Synthesis, Structures, and Optical Properties of Mo(W)/S(Se)/Ag Clusters: A Brief Overview

被引：15

作者：

Li, Jianghua ^{[1
]}

Zhang, Jinfang ^{[1
]}

Humphrey, Mark G. ^{[2
]}

Zhang, Chi ^{[1
]}

机构：

[1] Jiangsu Univ, Sci Res Acad, China Australia Joint Res Ctr Funct Mol Mat, Zhenjiang 212013, Peoples R China

[2] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 03期

基金：

中国国家自然科学基金;

关键词：

Cluster compounds; Silver; Tungsten; Molybdenum; Sulfur; Selenium; Structure elucidation; Nonlinear optics; Density functional calculations; OPEN HETEROTHIOMETALLIC CLUSTERS; CRYSTAL-STRUCTURE; POLYMERIC CLUSTERS; COORDINATION POLYMERS; ELECTRICAL-PROPERTIES; HELICAL CHAIN; COMPOUND; ANION; MO; LA;

D O I：

10.1002/ejic.201200735

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article provides a concise summary of recent research progress, including synthetic strategies, structural diversity, theoretical studies, and third-order nonlinear optical (NLO) properties, on Mo(W)/S(Se)/Ag heterobimetallic clusters. It offers a preliminary analysis of their metal-cation-directed synthesis, structures, and the subtle interplay of structural-functional relationships. Furthermore, DFT was used to provide an insight into the electronic transitions and spectral characterization of these clusters. Recent trends and perspectives of these clusters as NLO materials are also described.

引用

页码：328 / 346

页数：19

共 42 条

[41] Synthesis and characterisation of Group 6 metal carbonyl complexes of bis(ferrocenylchalcogeno) propanes:: X-ray crystal structures of [Cr(CO)4{FcTe(CH2)3TeFc}], [Mo(CO)4{FcE(CH2)3E′Fc}] (E=E′=Se;: E=Se, E′=Te;: E=E′=Te), and [W(CO)4{FcTe(CH2)3TeFc}] (Fc=[Fe(η5-C5H5)(η5-C5H4)])
Jing, Su
Morley, Christopher P.
Webster, Christopher A.
Di Vaira, Massimo
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (13) : 2310 - 2316
[42] Synthesis and characterization of chiral (mu(3)-S)FeCoM(CO)(8)(RCp) [M=Mo, W; R=C6H5C(O), CH3OC(O)C6H4C(O)] clusters and the crystal structures of (mu(3)-S)FeCoMo(CO)(8)[CH3OC(O)C6H4C(O)Cp] and (mu(3)-S)FeCoW(CO)(8)[CH3OC(O)C6H4C(O)Cp]
Ding, ER
Liu, SM
Yin, YQ
Sun, J
POLYHEDRON, 1997, 16 (19) : 3273 - 3278

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