Synthesis and structure of the polymeric cluster compound [Mn(H2O)4]3[W4S4(CN)12] • nH2O containing very large cavities

被引：9
作者：
Fedin, VP
Kalinina, IV
Virovets, AV
Fenske, D
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源：
RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 09期
关键词：
tungsten; cluster complexes; sulfide complexes; synthesis; X-ray diffraction analysis;
D O I：
10.1023/A:1013057712434
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The compound [Mn(H2O)(4)](3)[W4S4(CN)(12)]. nH(2)O (1) was prepared by the reaction of an aqueous solution of MnSO4 with a glycerol solution of KCs5[W4S4(CN)(12)].4H(2)O. Complex 1 was characterized by X-ray diffraction analysis and IR spectroscopy. According to the X-ray diffraction data, the three-dimensional polymeric framework of 1 comprises only 24.2% of the unit-cell volume. The volume of the cavities per formula unit is 1664 Angstrom(3). The cavities are occupied by highly disordered water molecules.
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收藏
页码：1525 / 1528
页数：4
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