Copper (I) bromide (CuBr): a highly efficient catalyst for the synthesis of β-enaminone derivatives using ultrasound irradiation under solvent-free conditions

被引：13

作者：

Redjemia, Rayenne ^{[1
]}

Bouzina, Abdeslem ^{[1
]}

Bouone, Yousra Ouafa ^{[1
]}

Mansouri, Achraf ^{[1
]}

Bahadi, Rania ^{[1
]}

Berredjem, Malika ^{[1
]}

机构：

[1] Badji Mokhtar Annaba Univ, Sci Fac, Dept Chem, Lab Appl Organ Chem,Synth Biomol & Mol Modelling, Box 1223000, Annaba, Algeria

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2022年 / 48卷 / 12期

关键词：

Enamination reaction; Ultrasound irradiation; Solvent-free; Copper bromide; SP(3) C-H; DICARBONYL COMPOUNDS; IONIC LIQUID; ESTERS; ENAMINATION; KETONES; MILD; ACID; ANTIBACTERIAL; COMBINATION;

D O I：

10.1007/s11164-022-04853-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of novel, clean, and efficient methods for the preparation of compounds is a major research focus in organic chemistry at the moment. In this context, copper bromide (CuBr) has been utilized as a heterogeneous catalyst for a highly efficient, eco-sustainable, and greener synthesis of beta-enaminone derivatives by condensation of 1,3-diketones with various primary amines at room temperature under ultrasound irradiation and solvent-free conditions. The structure of the synthesized compounds was confirmed by H-1, C-13 NMR spectroscopy, IR spectroscopy, and elemental analysis. The desired products were obtained in excellent yields (90-98%) within short reaction times (20-50 min).

引用

页码：4947 / 4962

页数：16

共 84 条

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