Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for "Click" Coupling

被引：17

作者：

Gerken, James B. ^{[1
]}

Rigsby, Matthew L. ^{[1
]}

Ruther, Rose E. ^{[1
]}

Perez-Rodriguez, Riviam J. ^{[1
]}

Guzei, Ilia A. ^{[1
]}

Hamers, Robert J. ^{[1
]}

Stahl, Shannon S. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 06期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

COVALENT ATTACHMENT; CHEMISTRY; MOLECULES; DYE; FUNCTIONALITY; INTERFACES; SURFACES; WATER;

D O I：

10.1021/ic302827s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A modular synthetic method has been developed for the preparation of Ru polypyridyl complexes bearing a terminal alkyne. This method proceeds through a readily accessible intermediate with a silyl-protected alkyne and allows access to a variety of five- and six-coordinate Ru complexes. These complexes can be easily attached to azide-functionalized electrode surfaces with only slight perturbation of the redox properties of the parent complex.

引用

收藏

页码：2796 / 2798

页数：3

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