Raman spectroscopy analysis of pigments on 16-17th c. Persian manuscripts

The palette of four Persian manuscripts of the 16th and 17th centuries were established by Raman microscopy to include lazurite, red lead, vermilion, orpiment, a carbon-based black, lead white, malachite, haematite, indigo, carmine and pararealgar. The first five pigments were identified on all four manuscripts, as previously found for other Islamic manuscripts of this period. The findings were compared with information available in treatises on Persian painting techniques. Red lead, although identified on all of the manuscripts analysed in this study as the main red pigment, is seldom mentioned in the literature. Two unusual pigments were also identified: the intermediate phase between realgar and pararealgar in the manuscript Timur namah, and carmine in the manuscript Shah namah. Although the established palette comprises few pigments, it was found that the illuminations were enhanced by the use of pigment mixtures, the components of which could be identified by Raman microscopy. (C) 2012 Elsevier B.V. All rights reserved.