Synthesis, crystal structure and physical properties of two new donor molecules

被引：12

作者：

Xiao, Xunwen ^{[1
]}

Wang, Guannan ^{[1
,2
]}

Shen, Liangjun ^{[1
]}

Fang, Jianghua ^{[1
]}

Gao, Haoqi ^{[1
]}

机构：

[1] Ningbo Univ Technol, Dept Chem Engn, Ningbo 315016, Zhejiang, Peoples R China

[2] Taiyuan Univ Technol, Dept Chem & Chem Engn, Taiyuan 030024, Peoples R China

来源：

SYNTHETIC METALS | 2012年 / 162卷 / 11-12期

基金：

中国国家自然科学基金;

关键词：

TTF derivative; Pyridine substitution; Donor-acceptor interaction; INTRAMOLECULAR CHARGE-TRANSFER; CU-II; TETRATHIAFULVALENE; COORDINATION; METAL; LIGANDS;

D O I：

10.1016/j.synthmet.2012.04.018

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Two ethylenedioxytetrathiafulvalenes substituted with a pyridinyl (Py) group (EDO-TTF-A) [A = 3-Py (1) and A = 4-Py (2)] have been synthesized to clear the nature of the donor-acceptor interaction between the TTF unit and a pyridine group, and characterized by H-1 NMR, mass spectra, elemental analyses and X-ray analysis. Cyclic voltammetry measurements show two steps of one-electron reversible waves with redox potentials comparable to other pyridine-substituted TTF derivatives, suggesting that these donor molecules, are much expected to produce a new pi/d system by complexation with d-spin carrying metal ions. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：900 / 903

页数：4

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