Synthesis, crystal structure and physical properties of two new donor molecules

被引：12
|
作者：
Xiao, Xunwen [1 ]
Wang, Guannan [1 ,2 ]
Shen, Liangjun [1 ]
Fang, Jianghua [1 ]
Gao, Haoqi [1 ]
机构：
[1] Ningbo Univ Technol, Dept Chem Engn, Ningbo 315016, Zhejiang, Peoples R China
[2] Taiyuan Univ Technol, Dept Chem & Chem Engn, Taiyuan 030024, Peoples R China
来源：
SYNTHETIC METALS | 2012年 / 162卷 / 11-12期
基金：
中国国家自然科学基金;
关键词：
TTF derivative; Pyridine substitution; Donor-acceptor interaction; INTRAMOLECULAR CHARGE-TRANSFER; CU-II; TETRATHIAFULVALENE; COORDINATION; METAL; LIGANDS;
D O I：
10.1016/j.synthmet.2012.04.018
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Two ethylenedioxytetrathiafulvalenes substituted with a pyridinyl (Py) group (EDO-TTF-A) [A = 3-Py (1) and A = 4-Py (2)] have been synthesized to clear the nature of the donor-acceptor interaction between the TTF unit and a pyridine group, and characterized by H-1 NMR, mass spectra, elemental analyses and X-ray analysis. Cyclic voltammetry measurements show two steps of one-electron reversible waves with redox potentials comparable to other pyridine-substituted TTF derivatives, suggesting that these donor molecules, are much expected to produce a new pi/d system by complexation with d-spin carrying metal ions. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：900 / 903
页数：4
相关论文
共 50 条
  • [1] Synthesis, crystal structure and selected properties of two new peroxidomolybdates
    Slawinska, Adrianna
    Serda, Pawel
    Oszajca, Marcin
    Pamin, Katarzyna
    Poltowicz, Jan
    Lasocha, Wieslaw
    POLYHEDRON, 2020, 183 (183)
  • [2] Synthesis, crystal structure, and properties of two metal complexes of imidazole and an ONO donor hydrazone
    Chen, Fengying
    Jin, Zhenguo
    Li, Hengxin
    He, Shuiyang
    JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (18) : 3146 - 3157
  • [3] Hydrothermal synthesis, crystal structure and physical properties of a new gadolinium phosphite hydrate
    Xiong, Ding-Bang
    Zhang, Zhi-Jun
    Gulay, Lubomir D.
    Tang, Mei-Bo
    Chen, Hao-Hong
    Yang, Xin-Xin
    Zhao, Jing-Tai
    INORGANICA CHIMICA ACTA, 2009, 362 (09) : 3013 - 3018
  • [4] Formation of Enantiomorphic Crystal From Achiral Molecules - Synthesis and Crystal Structure Determination of Two New Schiff Bases
    Sharma, Sanyog
    Kaur, Amanpreet
    Hundal, Maninder Singh
    Hundal, Geeta
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2013, 577 (01) : 73 - 82
  • [5] CeAsSe-Synthesis, Crystal Structure, and Physical Properties
    Schlechte, A.
    Niewa, R.
    Prots, Yu.
    Schnelle, W.
    Schmidt, M.
    Kniep, R.
    INORGANIC CHEMISTRY, 2009, 48 (05) : 2277 - 2284
  • [6] Crystal structure, electronic structure, and physical properties of two new antimonide-tellurides: ZrSbTe and HfSbTe
    Soheilnia, Navid
    Kleinke, Katja M.
    Kleinke, Holger
    CHEMISTRY OF MATERIALS, 2007, 19 (06) : 1482 - 1488
  • [7] Crystal structure and physical properties of two polymorphs of ropivacaine HCl
    Bergström, PO
    Fischer, A
    Kloo, L
    Sebhatu, T
    JOURNAL OF PHARMACEUTICAL SCIENCES, 2006, 95 (03) : 680 - 688
  • [8] Synthesis, crystal structure and physical properties of lanthanide beta''-aluminas
    Dedecke, T
    Kohler, J
    Tietz, F
    Urland, W
    EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1996, 33 (2-3): : 185 - 196
  • [9] Synthesis, Crystal Structure, and Physical Properties of BaSnS2
    Gunatilleke, Wilarachchige D. C. B.
    May, Andrew F.
    Walker, Angela R. Hight
    Biacchi, Adam J.
    Nolas, George S.
    PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2022, 16 (05):
  • [10] The Synthesis and Crystal Structure of Two New Hydrazone Compounds
    Wang, Li-Hua
    Tai, Xi-Shi
    CRYSTALS, 2016, 6 (05):
12345