The reactivity of lattice carbon and nitrogen species in molybdenum (oxy)carbonitrides prepared by single-source routes

被引：6

作者：

AlShalwi, M. ^{[1
]}

Hargreaves, J. S. J. ^{[1
]}

Liggat, J. J. ^{[2
]}

Todd, D. ^{[2
]}

机构：

[1] Univ Glasgow, WestCHEM, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland

[2] Univ Strathclyde, WestCHEM, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

MATERIALS RESEARCH BULLETIN | 2012年 / 47卷 / 05期

关键词：

Carbides; Nitrides; Thermogravimetric analysis; HEXAMETHYLENETETRAMINE COMPLEXES; REACTION SEQUENCE; NITRIDES; CARBIDES; DECOMPOSITION; CATALYSTS; CO3MO3N; METHANE; PHASE;

D O I：

10.1016/j.materresbull.2012.01.022

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Molybdenum (oxy)carbonitrides of different compositions have been prepared from hexamethylenetetramine molybdate and ethylenediamine molybdate precursors and the reactivity of the lattice carbon and nitrogen species within them has been determined by temperature programmed reduction and thermal volatilisation studies. Nitrogen is found to be much more reactive than carbon and the nature of its reactivity is influenced by composition with the presence of carbon enhancing the reactivity of nitrogen. The difference in reactivity observed indicates that molybdenum carbonitrides are not suitable candidates as reagents for which the simultaneous loss of nitrogen and carbon from the lattice would be desirable. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：1251 / 1256

页数：6

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