Dependence of ozone production on NO and hydrocarbons in the troposphere

被引:142
作者
Kleinman, LI
Daum, PH
Lee, JH
Lee, YN
Nunnermacker, LJ
Springston, SR
Newman, L
WeinsteinLloyd, J
Sillman, S
机构
[1] SUNY COLL OLD WESTBURY,DEPT CHEM PHYS,OLD WESTBURY,NY 11568
[2] UNIV MICHIGAN,DEPT ATMOSPHER OCEAN & SPACE SCI,ANN ARBOR,MI 48109
关键词
D O I
10.1029/97GL02279
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
An expression for the production rate of O-3, P(O-3), is derived based on a radical budget equation applicable to low and high NO, conditions. Differentiation of this equation with respect to NO or hydrocarbons (HC) gives an approximate analytic formula in which the relative sensitivity of P(O-3) to changes in NO or HC depends only on the fraction of radicals which are removed by reactions with NOx. This formula is tested by comparison with results from a photochemical calculation driven by trace gas observations from the 1995 Southern Oxidants Study (SOS) campaign in Nashville, Tennessee.
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页码:2299 / 2302
页数:4
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