A red fluorescence 'off-on' molecular switch for selective detection of Al3+, Fe3+ and Cr3+: experimental and theoretical studies along with living cell imaging

被引:175
作者
Goswami, Shymaprosad [1 ]
Aich, Krishnendu [1 ]
Das, Sangita [1 ]
Das, Avijit Kumar [1 ]
Sarkar, Deblina [2 ]
Panja, Sukanya [3 ]
Mondal, Tapan Kumar [2 ]
Mukhopadhyay, Subhrakanti [3 ]
机构
[1] Bengal Engn & Sci Univ, Dept Chem, Howrah, India
[2] Jadavpur Univ, Dept Chem, Kolkata, India
[3] Univ Burdwan, Dept Microbiol, Burdwan 713104, W Bengal, India
关键词
FRET-BASED SENSOR; TRIVALENT CATIONS; AQUEOUS-MEDIA; PROBE; CHEMOSENSOR; ALUMINUM; IONS; SPIROBENZOPYRAN; CHROMIUM(III); DISEASE;
D O I
10.1039/c3cc46860g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A spirobenzopyran-quinoline (SBPQ) based sensor was synthesized which selectively detects trivalent ions viz. Al3+, Fe3+ and Cr3+ through a fluorescence turn on signal in the red region (similar to 675 nm) with the detection limit in the order of 10(-8) M. The potentiality of the probe was confirmed by employing it for fluorescence bio-imaging with Al3+ in three different types of live-cells.
引用
收藏
页码:10739 / 10741
页数:3
相关论文
共 32 条
[1]   A new selective fluorogenic probe for trivalent cations [J].
Barba-Bon, Andrea ;
Costero, Ana M. ;
Gil, Salvador ;
Parra, Margarita ;
Soto, Juan ;
Martinez-Manez, Ramon ;
Sancenon, Felix .
CHEMICAL COMMUNICATIONS, 2012, 48 (24) :3000-3002
[2]   Aluminium speciation in relation to aluminium bioavailability, metabolism and toxicity [J].
Berthon, G .
COORDINATION CHEMISTRY REVIEWS, 2002, 228 (02) :319-341
[3]   A pyridinyl-functionalized tetraphenylethylene fluorogen for specific sensing of trivalent cations [J].
Chen, Xiujuan ;
Shen, Xiao Yuan ;
Guan, Erjia ;
Liu, Yi ;
Qin, Anjun ;
Sun, Jing Zhi ;
Tang, Ben Zhong .
CHEMICAL COMMUNICATIONS, 2013, 49 (15) :1503-1505
[4]   A highly selective and efficient single molecular FRET based sensor for ratiometric detection of Fe3+ ions [J].
Chereddy, Narendra Reddy ;
Thennarasu, Sathiah ;
Mandal, Asit Baran .
ANALYST, 2013, 138 (05) :1334-1337
[5]  
Committee on Animal Nutrition and National Research Council, 2007, ROL CHROM AN NUTR
[6]  
Fasman GD, 1996, COORDIN CHEM REV, V149, P125, DOI 10.1016/0010-8545(96)89157-0
[7]  
FISCHER E, 1952, J CHEM SOC, P4522
[8]   Redox signaling and cancer: The role of "labile" iron [J].
Galaris, Dimitrios ;
Skiada, Vasiliki ;
Barbouti, Alexandra .
CANCER LETTERS, 2008, 266 (01) :21-29
[9]   A switch in a cage with a memory [J].
Giordani, S ;
Raymo, FM .
ORGANIC LETTERS, 2003, 5 (20) :3559-3562
[10]   A highly selective and sensitive probe for colorimetric and fluorogenic detection of Cd2+ in aqueous media [J].
Goswami, Shyamaprosad ;
Aich, Krishnendu ;
Das, Sangita ;
Das, Avijit Kumar ;
Manna, Abhishek ;
Halder, Sandipan .
ANALYST, 2013, 138 (06) :1903-1907