Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions

被引：22

作者：

Zec, Nebojsa ^{[1
]}

Vranes, Milan ^{[1
]}

Bester-Rogac, Marija ^{[2
]}

-Petrovic, Tatjana Trtic Prime ^{[3
]}

Dimitrijevic, Aleksandra ^{[3
]}

Cobanov, Isidora ^{[1
]}

Gadzuric, Slobodan ^{[1
]}

机构：

[1] Univ Novi Sad, Fac Sci, Trg D Obradovica 3, Novi Sad 210003, Serbia

[2] Univ Ljubljana, Fac Chem & Technol, Ljubljana 1000, Slovenia

[3] Univ Belgrade, Inst Nucl Sci Vinca, Belgrade 11000, Serbia

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2018年 / 121卷

关键词：

Ionic liquids; Volumetric properties; Density; Imidazolium; Alkyl chain length; TEMPERATURE MOLTEN-SALTS; IMIDAZOLIUM; AMMONIUM; CATIONS; NEUTRALIZATION; STABILITY; MIXTURES; FLUORIDE; FEATURES; BINARY;

D O I：

10.1016/j.jct.2018.02.001

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this manuscript eight new 1,3-dialkylimidazolium bromide ionic liquids, [CnCmim][Br], were synthesized and characterized. Densities of ionic liquids and their diluted aqueous solutions have been measured over the whole composition range at selected temperatures from (293.15 to 323.15) K and at atmospheric pressure (p = 0.1 MPa). Influence of alkyl chain length and cation symmetry on densities and volumetric properties as well as nature of the interactions in aqueous [CnCmim][Br] solutions have been discussed and compared with previously published aqueous [C(2)C(4)im][Br] system. Densities of pure bromide based ionic liquids decrease with increasing alkyl chain length on imidazolium cation and depend on total number of methyl group in both side alkyl chains. Apparent molar volumes at infinite dilution of investigated ionic liquids in water increase linearly with increase of the total number of the C atoms in the side alkyl chain. (C) 2018 Elsevier Ltd.

引用

页码：72 / 78

页数：7

共 55 条

[11] Antibiofilm activities of 1-alkyl-3-methylimidazolium chloride ionic liquids [J].

Carson, Louise ;

Chau, Peter K. W. ;

Earle, Martyn J. ;

Gilea, Manuela A. ;

Gilmore, Brendan F. ;

Gorman, Sean P. ;

McCann, Maureen T. ;

Seddon, Kenneth R. .

GREEN CHEMISTRY, 2009, 11 (04) :492-497

[12] Does the variation of the alkyl chain length on N1 and N3 of imidazole ring affect physicochemical features of ionic liquids in the same way? [J].

Dozic, Sanja ;

Zec, Nebojsa ;

Tot, Aleksandar ;

Papovic, Snezana ;

Pavlovic, Ksenija ;

Gadzuric, Slobodan ;

Vranes, Milan .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2016, 93 :52-59

[13] Evaluation of Cd(II) transport with imidazolium bromides bearing butyl and isobutyl groups as extractants from acidic iodide solutions by liquid-liquid solvent extraction [J].

Eyupoglu, Volkan ;

Polat, Emrah .

FLUID PHASE EQUILIBRIA, 2015, 394 :46-60

[14] 1-alkyl-3-methylbenzotriazolium salts: ionic solvents and electrolytes [J].

Forsyth, SA ;

MacFarlane, DR .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (10) :2451-2456

[15] Flammability, thermal stability, and phase change characteristics of several trialkylimidazolium salts [J].

Fox, DM ;

Awad, WH ;

Gilman, JW ;

Maupin, PH ;

De Long, HC ;

Trulove, PC .

GREEN CHEMISTRY, 2003, 5 (06) :724-727

[16] Ionic liquids as electrolytes [J].

Galinski, Maciej ;

Lewandowski, Andrzej ;

Stepniak, Izabela .

ELECTROCHIMICA ACTA, 2006, 51 (26) :5567-5580

[17] Methanesulfonate and p-toluenesulfonate salts of the N-methyl-N-alkylpyrrolidinium and quaternary ammonium cations:: novel low cost ionic liquids [J].

Golding, J ;

Forsyth, S ;

MacFarlane, DR ;

Forsyth, M ;

Deacon, GB .

GREEN CHEMISTRY, 2002, 4 (03) :223-229

[18] Dynamic viscosities of a series of 1-alkyl-3-methylimidazolium chloride ionic liquids and their binary mixtures with water at several temperatures [J].

Gómez, E ;

González, B ;

Domínguez, A ;

Tojo, E ;

Tojo, J .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (02) :696-701

[19] Acidic 1-ethyl-3-methylimidazolium fluoride: a new room temperature ionic liquid [J].

Hagiwara, R ;

Hirashige, T ;

Tsuda, T ;

Ito, Y .

JOURNAL OF FLUORINE CHEMISTRY, 1999, 99 (01) :1-3

[20] Physicochemical properties of 1,3-dialkylimidazolium fluorohydrogenate room-temperature molten salts [J].

Hagiwara, R ;

Matsumoto, K ;

Nakamori, Y ;

Tsuda, T ;

Ito, Y ;

Matsumoto, H ;

Momota, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) :D195-D199

← 1 2 3 4 5 6 →