Effects of nano-silica on the strength development of geopolymer cured at room temperature

被引:155
作者
Deb, Partha Sarathi [1 ]
Sarker, Prabir Kumar [1 ]
Barbhuiya, Salim [1 ]
机构
[1] Curtin Univ, Dept Civil Engn, Perth, WA 6845, Australia
关键词
Blended fly ash; Compressive strength; Geopolymer; Microstructure; Nano-silica; FLY-ASH; ACTIVATION; WORKABILITY; NANOSILICA;
D O I
10.1016/j.conbuildmat.2015.10.044
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Use of nano-silica is gaining wider attention due to its significant effect on the microstructural and mechanical properties of Portland cement based binders. Effects of the incorporation of nano-silica in fly ash based geopolymer binders have been investigated in this study. Low-calcium fly ash was used as the principal source of aluminosilicate and it was blended with either blast furnace slag or Portland cement at small percentages in order to accelerate the curing at room temperature. Nano-silica was used at a rate up to 3% of the total binder in order to understand its effect on the strength and microstructural development. The experimental results show that the strength and microstructural properties could be further developed with inclusion of nano-silica in geopolymer mixes. Compressive strength increased with the increase of nano-silica content up to 2%. Scanning electron microscopy (SEM) images showed denser microstructures with well-connected interlocking morphology for the optimum nano-silica dosage. The strength increase is contributed by densification of the microstructure with the addition of nano-silica. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:675 / 683
页数:9
相关论文
共 56 条
[1]   Effect of nano-silica on strength and durability of fly ash based geopolymer mortar [J].
Adak, D. ;
Sarkar, M. ;
Mandal, S. .
CONSTRUCTION AND BUILDING MATERIALS, 2014, 70 :453-459
[2]   A study of HMDSO/O2 plasma deposits using a high-sensitivity and -energy resolution XPS instrument:: curve fitting of the Si 2p core level [J].
Alexander, MR ;
Short, RD ;
Jones, FR ;
Michaeli, W ;
Blomfield, CJ .
APPLIED SURFACE SCIENCE, 1999, 137 (1-4) :179-183
[3]  
American Society of testing materials, 2002, C109C109M ASTM
[4]   Comparative assessment of Australian fly ash and conventional concrete bricks [J].
Ayoko, GA ;
Lim, MCH ;
Olofinjana, A ;
Gilbert, D .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2005, 80 (03) :259-267
[5]   Geopolymeric materials prepared using Class F fly ash and elevated temperature curing [J].
Bakharev, T .
CEMENT AND CONCRETE RESEARCH, 2005, 35 (06) :1224-1232
[6]  
Belkowitz JS, 2015, ACI MATER J, V112, P419
[7]   Accelerating effects of colloidal nano-silica for beneficial calcium-silicate-hydrate formation in cement [J].
Björnström, J ;
Martinelli, A ;
Matic, A ;
Börjesson, L ;
Panas, I .
CHEMICAL PHYSICS LETTERS, 2004, 392 (1-3) :242-248
[8]  
Catherine A., 2007, AM CHEM SOC, V23, P9076
[9]   Determining the Reactivity of a Fly Ash for Production of Geopolymer [J].
Chen-Tan, Nigel W. ;
van Riessen, Arie ;
Ly, Chi V. ;
Southam, Daniel C. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (04) :881-887
[10]   Alkali activation of fly ashes.: Part 1:: Effect of curing conditions on the carbonation of the reaction products [J].
Criado, A ;
Palomo, A ;
Fernández-Jiménez, A .
FUEL, 2005, 84 (16) :2048-2054