Luminescence behavior of Ce3+ and Dy3+ codoped oxyfluoride glasses and glass ceramics containing LaF3 nanocrystals

被引:76
作者
Luo, Qun [1 ]
Qiao, Xvsheng [1 ]
Fan, Xianping [1 ]
Yang, Hui [1 ]
Zhang, Xianghua [2 ]
Cui, Shou [1 ]
Wang, Ling [1 ]
Wang, Gang [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
[2] Univ Rennes 1, CNRS, UMR Verres & Ceram 6512, Inst Chim Rennes, F-35042 Rennes, France
关键词
alumina; cerium compounds; dysprosium compounds; glass ceramics; impurity distribution; lanthanum compounds; nanostructured materials; photoluminescence; silicon compounds; RARE-EARTH IONS; ENERGY-TRANSFER; MULTIPHONON RELAXATION; ER3+ IONS; PHOSPHORS; EMISSION; BORATE; CERIUM;
D O I
10.1063/1.3077266
中图分类号
O59 [应用物理学];
学科分类号
摘要
The Ce3+ and Dy3+ codoped oxyfluoride glasses and glass ceramics containing LaF3 nanocrystals have been prepared in the reducing atmosphere. The emission intensity and Commission International de I'Eclairage (CIE) chromaticity coordinates of the Ce3+ and Dy3+ codoped glasses significantly changed with concentration ratio of Ce3+ to Dy3+. The emission intensity of both Ce3+ ions and Dy3+ ions in the 3.0% Ce3+ and 3.0% Dy3+ codoped glass ceramics increased significantly in comparison with that in the glass. The glasses and glass ceramics could emit bright white light by adjusting the concentration ratio of Ce3+ to Dy3+.
引用
收藏
页数:5
相关论文
共 26 条
[1]   QUANTUM EFFICIENCY OF DIFFUSION LIMITED ENERGY-TRANSFER IN LA1-X-YCEXTBYPO4 [J].
BOURCET, JC ;
FONG, FK .
JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (01) :34-39
[2]   Sr3B2O6:Ce3+,Eu2+:: A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes [J].
Chang, Chun-Kuei ;
Chen, Teng-Ming .
APPLIED PHYSICS LETTERS, 2007, 91 (08)
[3]   Improvement of Er3+ emissions in oxyfluoride glass ceramic nano-composite by thermal treatment [J].
Chen, Daqin ;
Wang, Yuansheng ;
Yu, Yunlong ;
Ma, En .
JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (05) :1445-1452
[4]   The luminescence and structure of novel transparent oxyfluoride glass-ceramics [J].
Dejneka, MJ .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 239 (1-3) :149-155
[5]   Formation and UV absorption of cerium, europium and terbium ions in different valencies in glasses [J].
Ebendorff-Heidepriem, H ;
Ehrt, D .
OPTICAL MATERIALS, 2000, 15 (01) :7-25
[6]  
Fasol S.N., 1997, BLUE LASER DIODE GAN
[7]  
HUANG H, 2007, APPL PHYS LETT, V90, DOI DOI 10.1063/1.2719028
[8]   Indirect energy transfer of Ce3+->Eu2+ in CaAl12O19 phosphor [J].
Jeon, HS ;
Kim, SK ;
Kim, SC ;
Park, SH ;
Park, HL ;
Mho, SI .
SOLID STATE COMMUNICATIONS, 1997, 102 (07) :555-559
[9]   Red-emitting cerium-based phosphor materials for solid-state lighting applications [J].
Le Toquin, R. ;
Cheetham, A. K. .
CHEMICAL PHYSICS LETTERS, 2006, 423 (4-6) :352-356
[10]   Luminescence properties of Tb3+-Sm3+ codoped glasses for white light emitting diodes [J].
Liang, Xiaoluan ;
Yang, Yunxia ;
Zhu, Chaofeng ;
Yuan, Shuanglong ;
Chen, Guorong ;
Pring, Allan ;
Xia, Fang .
APPLIED PHYSICS LETTERS, 2007, 91 (09)