Paper-structured catalyst for the steam reforming of biodiesel fuel

被引：27

作者：

Shiratori, Yusuke ^{[1
,2
,3
]}

Quang-Tuyen, Tran ^{[1
]}

Umemura, Yuuka ^{[4
]}

Kitaoka, Takuya ^{[4
]}

Sasaki, Kazunari ^{[1
,2
,3
,5
]}

机构：

[1] Kyushu Univ, Fac Engn, Nishi Ku, Fukuoka 8190395, Japan

[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI, Fukuoka 8190395, Japan

[3] Kyushu Univ, Next Generat Fuel Cell Res Ctr, Nishi Ku, Fukuoka 8190395, Japan

[4] Kyushu Univ, Fac Agr, Higashi Ku, Fukuoka 8128581, Japan

[5] Kyushu Univ, Int Res Ctr Hydrogen Energy, Nishi Ku, Fukuoka 8190395, Japan

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2013年 / 38卷 / 26期

关键词：

Steam reforming; Palm biodiesel; Paper-structured catalyst; Solid oxide fuel cell; ACID; CH4; OXIDATION; PFAD;

D O I：

10.1016/j.ijhydene.2013.06.080

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Architectonics of the paper-structured catalyst for the application to the biofuel reformer or direct internal reforming SOFC (DIRSOFC) was studied. Inorganic fiber network, "paper", composed of yttria-stabilized zirconia (YSZ) fiber (Zf), alumina fiber (Af) and inorganic binder (Al2O3 sol (As) or ZrO2 sol (Zs) or CeO2 sol (Cs)) was prepared by a simple paper-making process. Then, the catalytic activities of the Ni and Ni-MgO loaded papers called "paper-structured catalysts (PSCs)" for the steam reforming of biodiesel fuels (BDFs) were evaluated. Ni-MgO loaded PSC using Cs as an inorganic binder, Ni-MgO/ZfAfCs, exhibited excellent performance over Ru/gamma Al2O3 catalyst beads. Formation of light hydrocarbons, especially C2H4, was eliminated and water gas shift reaction was more promoted compared to the catalyst beads. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：11278 / 11287

页数：10

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