Efficient rhodium catalysts for the hydrogenolysis of thiophenic molecules in homogeneous phase

被引：37

作者：

Bianchini, C ^{[1
]}

Casares, JA ^{[1
]}

Meli, A ^{[1
]}

Sernau, V ^{[1
]}

Vizza, F ^{[1
]}

SanchezDelgado, RA ^{[1
]}

机构：

[1] INST VENEZOLANO INVEST CIENT,CARACAS 10020A,VENEZUELA

来源：

POLYHEDRON | 1997年 / 16卷 / 18期

关键词：

hydrodesulfurization; catalysis; thiophenes; rhodium; HPNMR spectroscopy;

D O I：

10.1016/S0277-5387(96)00541-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of strong bases, the C-S insertion complexes (triphos)Rh[eta(3)-S(C6H4)CH=CH2] and (triphos)Rh(eta(3)-SCH=CH CH=CH2) as well as the pi-alkyne complex [(triphos)Rh(eta(2)-MeO2CC=CCO2 Me)]PF6 are catalyst precursors for the hydrogenation of thiophene (T), benzo[b]thiophene (BT) and dibenzo[b,d]thiophene (DBT) in tetrahydrofuran solution [triphos = MeC(CH2PPh2)(3)]. Both hydrogenolysis (thiols) and desulfurization (hydrocarbons) products are obtained. Among the substrates investigated, BT is the most reactive, whereas T is the easiest to desulfurize. (C) 1997 Elsevier Science Ltd.

引用

页码：3099 / 3114

页数：16

共 87 条

[1] FORMATION OF BUTENETHIOLATE BY THE RING-OPENING OF TETRAHYDROTHIOPHENE BY A TRIOSMIUM CLUSTER COMPLEX
ADAMS, RD
POMPEO, MP
WU, WG
YAMAMOTO, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) : 8207 - 8213
[2] AMORELLI A, 1992, HYDROCARBON PROC JUN, P93
[3] ANGELICI RJ, 1995, B SOC CHIM BELG, V104, P265
[4] STRUCTURAL ASPECTS OF THIOPHENE COORDINATION IN TRANSITION-METAL COMPLEXES
ANGELICI, RJ
[J]. COORDINATION CHEMISTRY REVIEWS, 1990, 105 : 61 - 76
[5] HETEROGENEOUS CATALYSIS OF THE HYDRODESULFURIZATION OF THIOPHENES IN PETROLEUM - AN ORGANOMETALLIC PERSPECTIVE OF THE MECHANISM
ANGELICI, RJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (11) : 387 - 394
[6] [Anonymous], ENCY INORGANIC CHEM
[7] THIOPHENE C-S BOND-CLEAVAGE BY RHODIUM AND IRIDIUM - AN UNPRECEDENTED BRIDGING MODE OF THE OPEN C4H4S FRAGMENT
BACCHI, A
BIANCHINI, C
HERRERA, V
JIMENEZ, MV
MEALLI, C
MELI, A
MONETI, S
PERUZZINI, M
SANCHEZDELGADO, RA
VIZZA, F
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (09) : 921 - 922
[8] STUDIES OF THE MECHANISM OF THIOPHENE HYDRODESULFURIZATION - H-2 NMR AND MASS-SPECTRAL ANALYSIS OF 1,3-BUTADIENE PRODUCED IN THE DEUTERODESULFURIZATION (DDS) OF THIOPHENE OVER PBMO6S8 CATALYST
BENSON, JW
SCHRADER, GL
ANGELICI, RJ
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 96 (03) : 283 - 299
[9] HOMOGENEOUS REACTIONS OF THIOPHENES WITH TRANSITION-METALS - A MODELING APPROACH FOR ELUCIDATION OF THE HYDRODESULFURIZATION MECHANISM AND AN EFFECTIVE METHOD FOR THE SYNTHESIS OF UNUSUAL ORGANOSULFUR COMPOUNDS
BIANCHINI, C
FREDIANI, P
HERRERA, V
JIMENEZ, MV
MELI, A
RINCON, L
SANCHEZDELGADO, R
VIZZA, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (15) : 4333 - 4346
[10] HYDRODESULFURIZATION (HDS) MODEL SYSTEMS - OPENING, HYDROGENATION, AND HYDRODESULFURIZATION OF DIBENZOTHIOPHENE (DBT) AT IRIDIUM - FIRST CASE OF CATALYTIC HDS OF DBT IN HOMOGENEOUS PHASE
BIANCHINI, C
JIMENEZ, MV
MELI, A
MONETI, S
VIZZA, F
HERRERA, V
SANCHEZDELGADO, RA
[J]. ORGANOMETALLICS, 1995, 14 (05) : 2342 - 2352

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