Electrochemical investigation of a new Cu-MOF and its electrocatalytic activity towards H2O2 oxidation in alkaline solution

被引:121
作者
Zhang, Chengyan [1 ,2 ]
Wang, Mingyan [2 ]
Liu, Lin [2 ]
Yang, Xujie [1 ]
Xu, Xingyou [1 ,3 ]
机构
[1] Nanjing Univ Sci & Technol, Minist Educ, Key Lab Soft Chem & Funct Mat, Nanjing 210094, Jiangsu, Peoples R China
[2] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222005, Peoples R China
[3] Huaiyin Inst Technol, Huaiyin 223003, Peoples R China
关键词
Metal-organic framework; Electrochemical behaviour; Hydrogen peroxide; Electrocatalysis; METAL-ORGANIC FRAMEWORKS; HYDROGEN-PEROXIDE; COPPER(II); REDUCTION; BEHAVIOR; COMPLEX; LIGAND; STABILIZATION; COMPOSITE; ELECTRODE;
D O I
10.1016/j.elecom.2013.04.026
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A new Cu metal-organic framework (Cu-MOF), [Cu(adp)(BIB)(H2O)](n) (BIB = 1,4-bisimidazolebenzene; H(2)adp = adipic acid), is synthesised under hydrothermal conditions. Single-crystal X-ray analysis reveals a three-dimensional supramolecular architecture with channels originating from two-dimensional layers extended by hydrogen bonds. The cyclic voltammogram of a [Cu(adp)(BIB)(H2O)](n)-modified electrode shows a pair of redox peaks at ca. 0.43 V in 0.1 M NaOH solution corresponding to Cu-III(OH)-MOF/Cu-II(H2O)-MOF couple. The Cu-MOF-modified electrode shows high electrocatalytic activity towards H2O2 oxidation with a linear range from 0.1 mu M to 2.75 mu M and a detection limit of 0.068 mu M. Thus, Cu-MOF is a promising material for H2O2 detection. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:131 / 134
页数:4
相关论文
共 20 条
[1]   The Trivalent Copper Complex of a Conjugated Bis-dithiocarbazate Schiff Base: Stabilization of Cu in Three Different Oxidation States [J].
Ali, Mohammad Akbar ;
Bernhardt, Paul V. ;
Brax, Mathilde A. H. ;
England, Jason ;
Farlow, Anthony J. ;
Hanson, Graeme R. ;
Yeng, Lee Len ;
Mirza, Aminul Huq ;
Wieghardt, Karl .
INORGANIC CHEMISTRY, 2013, 52 (03) :1650-1657
[2]   LIGAND EFFECTS ON THERMODYNAMIC STABILIZATION OF COPPER(III)-PEPTIDE COMPLEXES [J].
BOSSU, FP ;
CHELLAPPA, KL ;
MARGERUM, DW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) :2195-2203
[3]   Catalytic behavior of Co3O4 in electroreduction of H2O2 [J].
Cao, Dianxue ;
Chao, Jundang ;
Sun, Limei ;
Wang, Guiling .
JOURNAL OF POWER SOURCES, 2008, 179 (01) :87-91
[4]  
Carballo R, 2007, CRYST GROWTH DES, V7, P1069, DOI [10.1021/cg060616l, 10.1021/cg0606161]
[5]   Recent advances in electrochemical sensing for hydrogen peroxide: a review [J].
Chen, Wei ;
Cai, Shu ;
Ren, Qiong-Qiong ;
Wen, Wei ;
Zhao, Yuan-Di .
ANALYST, 2012, 137 (01) :49-58
[6]   Electrochemistry of metal-organic frameworks:: A description from the voltammetry of microparticles approach [J].
Domenech, Antonio ;
Garcia, Hermenegildo ;
Domenech-Carbo, Maria Teresa ;
Xamena, F. X. L. I. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (37) :13701-13711
[7]   An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction [J].
Fu, Yanghe ;
Sun, Dengrong ;
Chen, Yongjuan ;
Huang, Renkun ;
Ding, Zhengxin ;
Fu, Xianzhi ;
Li, Zhaohui .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (14) :3364-3367
[8]   Electrocatalytically Active Graphene-Porphyrin MOF Composite for Oxygen Reduction Reaction [J].
Jahan, Maryam ;
Bao, Qiaoliang ;
Loh, Kian Ping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (15) :6707-6713
[9]   Trinuclear Cobalt Based Porous Coordination Polymers Showing Unique Topological and Magnetic Variety upon Different Dicarboxylate-like Ligands [J].
Luo, Feng ;
Che, Yun-xia ;
Zheng, Ji-min .
CRYSTAL GROWTH & DESIGN, 2009, 9 (02) :1066-1071
[10]   Electrocatalytic four-electron reduction of oxygen with Copper (II)-based metal-organic frameworks [J].
Mao, Junjie ;
Yang, Lifen ;
Yu, Ping ;
Wei, Xianwen ;
Mao, Lanqun .
ELECTROCHEMISTRY COMMUNICATIONS, 2012, 19 :29-31