On the Way to an Oxidative Hosomi-Sakurai Reaction

被引：40

作者：

Sabot, Cyrille ^{[1
]}

Commare, Bruno ^{[1
]}

Duceppe, Marc-Alexandre ^{[1
]}

Nahi, Salima ^{[1
]}

Guerard, Kimiaka C. ^{[1
]}

Canesi, Sylvain ^{[1
]}

机构：

[1] Univ Quebec, Lab Methodol & Synth Prod Nat, Montreal, PQ H3C 3P8, Canada

来源：

SYNLETT | 2008年 / 20期

基金：

加拿大自然科学与工程研究理事会;

关键词：

hypervalent iodine; allyltrimethylsilane; substitued phenols; oxidative allylation;

D O I：

10.1055/s-0028-1087369

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An oxidative allylation process mediated by a hypervalent iodine reagent has been performed on polysubstituted phenols. This reaction, occurring in useful to good yields, leads to a rapid access to dienones containing a quaternary carbon center.

引用

页码：3226 / 3230

页数：5