On the Way to an Oxidative Hosomi-Sakurai Reaction

被引：40
|
作者：
Sabot, Cyrille [1 ]
Commare, Bruno [1 ]
Duceppe, Marc-Alexandre [1 ]
Nahi, Salima [1 ]
Guerard, Kimiaka C. [1 ]
Canesi, Sylvain [1 ]
机构：
[1] Univ Quebec, Lab Methodol & Synth Prod Nat, Montreal, PQ H3C 3P8, Canada
来源：
SYNLETT | 2008年 / 20期
基金：
加拿大自然科学与工程研究理事会;
关键词：
hypervalent iodine; allyltrimethylsilane; substitued phenols; oxidative allylation;
D O I：
10.1055/s-0028-1087369
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An oxidative allylation process mediated by a hypervalent iodine reagent has been performed on polysubstituted phenols. This reaction, occurring in useful to good yields, leads to a rapid access to dienones containing a quaternary carbon center.
引用
收藏
页码：3226 / 3230
页数：5
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