Oxidation and reductive bromination of Bis(4-tert-butylphenyl)aminoxyl

被引：2

作者：

Golubev, V. A. ^{[1
]}

Sen', V. D. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 49卷 / 08期

关键词：

MeCN; Bromine Atom; Tribromide; Oxoammonium; Aminyl;

D O I：

10.1134/S1070428013080083

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One-electron oxidation of bis(4-tert-butylphenyl)aminoxyl with antimony pentachloride and bromine leads to the formation of oxoammonium salts with anions SbCl (6) (-) and Br (3) (-) respectively. The salt with the Br (3) (-) anion converted at heating into a mixture of bromodiphenylamines which formed also from the aminoxyl as a result of previously unknown reaction of three-electron reductive bromination. The mechanisms of these reactions were assumed.

引用

页码：1143 / 1149

页数：7

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