Using Gas-Phase Clusters to Screen Porphyrin-Supported Nanocluster Catalysts for Ethane Oxidation to Ethanol

被引：11

作者：

Pellizzeri, Steven ^{[1
]}

Jones, Isaac A. ^{[1
]}

Doan, Hieu A. ^{[2
]}

Snurr, Randall Q. ^{[2
]}

Getman, Rachel B. ^{[1
]}

机构：

[1] Clemson Univ, Dept Chem & Biomol Engn, Clemson, SC 29634 USA

[2] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

来源：

CATALYSIS LETTERS | 2016年 / 146卷 / 12期

关键词：

Nanocluster catalysts; Heterogeneous catalysis; Kinetic modeling; Computational catalysis; ATOMIC LAYER DEPOSITION; HETEROGENEOUS CATALYSIS; SCALING RELATIONSHIPS; ELECTRONIC-STRUCTURE; SITE; METHANE; STABILITY; TEMPERATURE; CONVERSION; HYDROGEN;

D O I：

10.1007/s10562-016-1890-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We demonstrate the use of gas phase metal hydroxide clusters to identify descriptors and generate scaling relationships for predicting catalytic performances of porphyrin-supported metal hydroxide catalysts. Using the gas phase clusters for these purposes takes just 5 % of the time that would have been required if the porphyrin-supported models had been used. [GRAPHICS] .

引用

页码：2566 / 2573

页数：8

共 44 条

[1] Using Gas-Phase Clusters to Screen Porphyrin-Supported Nanocluster Catalysts for Ethane Oxidation to Ethanol
Steven Pellizzeri
Isaac A. Jones
Hieu A. Doan
Randall Q. Snurr
Rachel B. Getman
Catalysis Letters, 2016, 146 : 2566 - 2573
[2] Gas-Phase Oxidation of Aqueous Ethanol by Nanoparticle Vanadia/Anatase Catalysts
Jorgensen, Betina
Kristensen, Steffen Buus
Kunov-Kruse, Andreas Jonas
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Christensen, Claus Hviid
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TOPICS IN CATALYSIS, 2009, 52 (03) : 253 - 257
[3] Gas-Phase Oxidation of Aqueous Ethanol by Nanoparticle Vanadia/Anatase Catalysts
Betina Jørgensen
Steffen Buus Kristensen
Andreas Jonas Kunov-Kruse
Rasmus Fehrmann
Claus Hviid Christensen
Anders Riisager
Topics in Catalysis, 2009, 52 : 253 - 257
[4] Selective gas-phase oxidation of ethanol by molecular oxygen over oxide and gold-containing catalysts
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090, Russia
不详
Catal. Ind., 2012, 4 (247-252): : 247 - 252
[5] Partial oxidation of methane on silica-supported vanadia catalysts. The relevance of catalyst BET area and gas-phase activation
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Lu, Xiaoqing
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[7] Rutile TiO2-Supported Pt Nanoparticle Catalysts for the Low-Temperature Oxidation of Ethane to Ethanol
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Kimura, Yuya
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (29) : 20122 - 20132
[8] On the metal-support synergy for selective gas-phase ethanol oxidation over MgCuCr2O4 supported metal nanoparticle catalysts
Liu, Peng
Zhu, Xiaochun
Yang, Shuibin
Li, Tao
Hensen, Emiel J. M.
JOURNAL OF CATALYSIS, 2015, 331 : 138 - 146
[9] Catalytic oxidation of CO with N2O on gas-phase platinum clusters
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Balteanu, I
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Bondybey, VE
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (47) : 6519 - 6522
[10] An Experimental Study on the Early Stages of Gas-Phase Olefin Polymerizations Using Supported Ziegler-Natta and Metallocene Catalysts
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