Increasing the initiation efficiency of ruthenium-based ring-opening metathesis initiators: Effect of excess phosphine

被引：91

作者：

Bielawski, CW ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

MACROMOLECULES | 2001年 / 34卷 / 26期

关键词：

D O I：

10.1021/ma011214j

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymers with narrow polydispersities were obtained from ROMP initiator when commercially available phosphines were included. Similar to controlled radical polymerizations, it was shown that enhanced control is related to a fast, dynamic equilibrium that exists between dormant and active species and is mediated by the type and quantity of phosphine employed.

引用

页码：8838 / 8840

页数：3

共 11 条

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