The kinetic study on the anionic polymerization of isoprene

被引：0

作者：

Cheng, J ^{[1
]}

Han, BY ^{[1
]}

Yang, H ^{[1
]}

He, CF ^{[1
]}

Jin, GT ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China

来源：

CHINESE JOURNAL OF CHEMICAL ENGINEERING | 1999年 / 7卷 / 02期

关键词：

anionic polymerization; isoprene; kinetics; microstructure;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetic study of the anionic polymerization of isoprene is carried out in tetrahydrofuran(TMF), using n-BuLi as initiator. Kinetic parameters are obtained, which comprise chain propagation rate constant, k(p) and partial rate constants, k(3) and k(4) + k(5), propagation orders with respect to monomer and active species concentrations, alpha and-beta, real activation energy, E, as well as partial activation energies, E-3 and E4+5 and so on. The relationship between the microstructure of polyisoprene and the ratio of [THF]/[n-BuLi] has been investigated. On the basis of the studies mentioned above, a reasonable mechanism of the anionic polymerization of isoprene in THF is proposed.

引用

页码：154 / 160

页数：7