Abnormal Carbenes as Ligands in Transition Metal Chemistry: Curiosities with Exciting Perspectives

被引：44

作者：

Albrecht, Martin ^{[1
]}

机构：

[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland

来源：

CHIMIA | 2009年 / 63卷 / 03期

基金：

瑞士国家科学基金会;

关键词：

Abnormal coordination mode; Catalytic applications; N-Heterocyclic carbenes; Late transition metals; Metal nucleophilicity; N-HETEROCYCLIC CARBENES; C-H ACTIVATION; IMIDAZOLIUM SALTS; PALLADIUM COMPLEXES; IRIDIUM COMPLEXES; RHODIUM(III) COMPLEXES; REDUCTIVE ELIMINATION; STABLE CARBENE; CATALYSTS; BINDING;

D O I：

10.2533/chimia.2009.105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review compiles the advances achieved in our laboratories using abnormal and less heteroatom-stabilized carbenes as ligands for transition metal chemistry. Fundamental studies allowed the evaluation of the impact of this new class of ligands both electronically and sterically. Based on these results, initial catalytic applications have been devised in the area of H-H and C-H bond activation, demonstrating the potential of abnormal carbenes as unique ligands for transition metals.

引用

页码：105 / 110

页数：6

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