An effective oxide shell-protected surface-enhanced Raman scattering (SERS) substrate: the easy route to Ag@AgxO-silicon nanowire films via surface doping

被引:25
作者
Liao, Fan [1 ]
Cheng, Liang [1 ]
Li, Jing [1 ]
Shao, Mingwang [1 ]
Wang, Zhenghua [2 ]
Lee, Shuit-Tong [1 ]
机构
[1] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Peoples R China
[2] Anhui Normal Univ, Coll Chem & Mat Sci, Anhui Key Lab Funct Mol Solids, Wuhu, Peoples R China
基金
中国国家自然科学基金;
关键词
SILVER NANOPARTICLES; MOLECULES; ARRAYS;
D O I
10.1039/c2tc00761d
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper reported the fabrication of an ultrathin silver oxide shell covered silver nanoparticles embedded in silicon nanowire film (Ag@AgxO-SiNW) by a facile method. The amorphous ultrathin silver oxide layers, which can keep Ag nanoparticles from agglomerating, were confirmed by HRTEM and STEM mapping. The Ag@AgxO-SiNW was employed as a surface-enhanced Raman scattering substrate and exhibited excellent enhancement for the concentration detection (1 x 10(-7) M) of rhodamine 6 G and crystal violet with the relative standard deviation of the main Raman vibration modes less than 20%. This core@shell structure may be explained by the surface doping of silicon nanowires.
引用
收藏
页码:1628 / 1632
页数:5
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