Cyclopalladated complexes with functionalized diphosphines via activation of chelated 1,1-bis(diphenylphosphino)ethene

被引：11

作者：

Teijido, B ^{[1
]}

Fernández, AA

López-Torres, M

Suárez, A

Vila, JM

Mosteiro, R

Fernández, JJ

机构：

[1] Univ Santiago de Compostela, Dept Quim Inorgan, Santiago De Compostela 15782, Spain

[2] Univ A Coruna, Dept Quim Fundamental, La Coruna 15071, Spain

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 06期

关键词：

D O I：

10.1021/om0106884

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1 with 1,1-bis(diphenylphosphino)ethene (vdpp) gave the mononuclear cyclometalated compound 2. The withdrawing effect of the cyclopalladated moiety suffices to polarize the C=CH2 double bond to afford the addition products 3-8, by treatment of complex 2 with primary aliphatic and aromatic amines. The molecular structures of 2, 4, and 8 have been determined by X-ray crystallography, showing that the C-C distance in 4 and 8 has the expected single-bond length upon addition.

引用

页码：1304 / 1307

页数：4

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