Bis{2-methoxy-6-[(4-methylphenyl)-iminiomethyl]phenolato-κO1}bis(thiocyanato-κN) zinc(II)

被引：4

作者：

Li, Hua-Qiong

Xian, Hui-Duo

Liu, Jian-Feng

Zhao, Guo-Liang ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808035368

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Schiff base 2-[(4-methylphenyl)iminomethyl]-6-methoxy-phenol (HL) forms a complex with a Zn2+ atom and two independent thiocyanate ions, [Zn(NCS)(2)(C15H15NO2)(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn2+ atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thiocyanate ligands. The coordination environment of the Zn atom is distorted-tetrahedral.

引用

页码：M1495 / U126

页数：11

共 13 条

[1]

Bruker, 2004, APEX2 SAINT

[2] 1,2,4-TRIAZOLE COMPLEXES .18. STRUCTURE OF BIS(4-TERT-BUTYL-1,2,4-TRIAZOLE-N-1)BIS(ISOTHIOCYANATO)ZINC(II) [J].

GROENEVELD, LR ;

VOS, G ;

GORTER, S ;

HAASNOOT, JG .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (AUG) :2248-2250

[3] Bis{(E)-6-methoxy-2-[(4-methylphenyl)-iminomethyl] phenolato}cobalt(II) [J].

Iyere, PA ;

Boadi, WY ;

Ross, L .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M304-M306

[4] Bis(thiocyanato-κN)bis(triphenyl-phosphine oxide-κO)zinc(II) [J].

Li, Yinhuai .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M2359-U1019

[5] SYNTHESIS, MAGNETIC AND SPECTRAL STUDIES OF SOME MIXED-LIGAND COMPLEXES OF COPPER(II) AND COBALT(II) WITH SCHIFF-BASES AND 2-PYRAZOLINE-5-ONE OR 3-PYRAZOLINE-5-ONE DERIVATIVES [J].

MAURYA, RC ;

MISHRA, DD ;

RATHORE, R ;

JAIN, S .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1994, 24 (03) :427-439

[6] Ligating properties of a potentially tetradentate Schiff base [(CH3)2NCH2CH2N = CHC6H3(OH)(OMe)] with zinc(II), cadmium(II), cobalt(II), cobalt(III) and manganese(III) ions:: synthesis and structural studies [J].

Sen, S ;

Talukder, P ;

Dey, SK ;

Mitra, S ;

Rosair, G ;

Hughes, DL ;

Yap, GPA ;

Pilet, G ;

Gramlich, V ;

Matsushita, T .

DALTON TRANSACTIONS, 2006, (14) :1758-1767

[7]

Sheldrick G.M., 1996, SADABS VERSION 2008

[8] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[9]

Yu YY, 2007, CHINESE J STRUC CHEM, V26, P1395

[10] {2-[3-(dimethylammonio)propyliminomethyl]-6-methoxyphenolato} diisothiocyanatozinc(II)chloroform solvate [J].

Zhang, Qi-Wei ;

Wang, Gui-Xian .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 :m652-m653

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