Luminescent Triarylboron-Functionalized Zinc Carboxylate Metal-Organic Framework

被引：55
作者：
Blight, Barry A. [1 ]
Guillet-Nicolas, Remy [2 ]
Kleitz, Freddy [2 ]
Wang, Rui-Yao [1 ]
Wang, Suning [1 ]
机构：
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Univ Laval, Dept Chem, Quebec City, PQ G1V 0A6, Canada
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 04期
基金：
加拿大自然科学与工程研究理事会;
关键词：
PROTON CONDUCTION; HYDROGEN; MOFS; MOLECULES; EMISSION; STORAGE;
D O I：
10.1021/ic3020223
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal-organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a (ZnB)-B-II-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and similar to 21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N-2, argon, and CO2.
引用
收藏
页码：1673 / 1675
页数：3
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