Efficient and enantioselective nitroaldol reaction catalyzed by copper Schiff-base complexes

被引：103

作者：

Gan, CS

Lai, GY

Zhang, ZH

Wang, ZY

Zhou, MM ^{[1
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[3] NYU, Mt Sinai Sch Med, Dept Physiol & Biophys, Struct Biol Program, New York, NY 10029 USA

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 05期

基金：

美国国家卫生研究院; 中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tetasy.2006.01.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mild and efficient enantioselective nitroaldol reactions of nitromethane with various aldehydes were catalyzed by chiral copper Schiff-base complexes, which can be readily prepared from amino acid, yielding the corresponding adducts with high yields and good enantiometric excess (ee). (c) 2006 Elsevier Ltd. All rights reserved.

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页码：725 / 728

页数：4

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