Transparent self-cleaning coating of modified polydimethylsiloxane (PDMS) for real outdoor application

被引:55
作者
Syafiq, A. [1 ]
Vengadaesvaran, B. [1 ]
Abd Rahim, Nasrudin [1 ,2 ]
Pandey, A. K. [3 ]
Bushroa, A. R. [4 ]
Ramesh, K. [5 ]
Ramesh, S. [5 ]
机构
[1] Univ Malaya, UM Power Energy Dedicated Adv Ctr UMPEDAC, Level 4,Jalan Pantai Baharu, Kuala Lumpur 59990, Malaysia
[2] King Abdulaziz Univ, Renewable Energy Res Grp, Jeddah 21589, Saudi Arabia
[3] Sunway Univ, Sch Sci & Technol, Res Ctr Nanomat & Energy Technol RCNMET, 5 Jalan Univ, Petaling Jaya 47500, Selangor, Malaysia
[4] Univ Malaya, Fac Engn, AMMP Ctr, Level 8,Engn Tower, Kuala Lumpur 50603, Malaysia
[5] Univ Malaya, Dept Phys, Ctr Ion, Kuala Lumpur 50603, Malaysia
关键词
PDMS: APTES; GLYMO; Hydrophobic; Self-cleaning; Anti-fog; SUPERHYDROPHOBIC SURFACES; MECHANICAL-PROPERTIES; FABRICATION; DURABILITY; COMPOSITE; TEMPLATE; BEHAVIOR; ANGLES; FILMS; FOG;
D O I
10.1016/j.porgcoat.2019.02.020
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Hydrophobic coating usually possesses a water contact angle (CA) of more than 90 degrees. The fabrication of hydrophobic coating on the glass substrate has high potential to induce self-cleaning properties, anti-fogging and mud-repellent properties. In this study, a transparent hydrophobic self-cleaning coating with modified Polydimethylsiloxane (PDMS) has been successfully developed using 3-aminopropyltriethoxyslane (APTES). APTES has a flexible amino group for silica structuration of Polydimethylsiloxane to cross-link and form a hybrid coating system. The hydrophobic coating developed is applied onto glass plates using dip-coating method. The hydrophobicity of the coating is tested using the water contact angle (WCA) method and achieved WCA as high as 103.9 degrees. The UV-VIS spectrometer measurement reveals that the transparency of the modified APTES/PDMS coating is above 90% in visible region. The prepared hybrid coating also exhibits excellent self-cleaning properties in indoor and outdoor environment. In addition to that, the hybrid coating also exhibits great anti-fogging behavior where the tiny water droplets on the coated surface completely disappear after 6 min at ambient temperature.
引用
收藏
页码:232 / 239
页数:8
相关论文
共 59 条
[1]  
Alireza R., 2017, MECH BIOL EVALUATION
[2]   A simple and scalable approach towards the preparation of superhydrophobic surfaces - importance of the surface roughness skewness [J].
Boscher, Nicolas D. ;
Vache, Veronique ;
Carminati, Paul ;
Grysan, Patrick ;
Choquet, Patrick .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (16) :5744-5750
[3]   Single-Step Process for the Deposition of High Water Contact Angle and High Water Sliding Angle Surfaces by Atmospheric Pressure Dielectric Barrier Discharge [J].
Boscher, Nicolas D. ;
Duday, David ;
Verdier, Stephane ;
Choquet, Patrick .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (03) :1053-1060
[4]   THE EFFECT OF SURFACE FOG ON THE TRANSMITTANCE OF LIGHT [J].
BRISCOF, BJ ;
GALVIN, KP .
SOLAR ENERGY, 1991, 46 (04) :191-197
[5]  
Bunshah R.F., 2001, HDB HARD COATINGS
[6]   Fabrication of All-Water-Based Self-Repairing Superhydrophobic Coatings Based on UV-Responsive Microcapsules [J].
Chen, Kunlin ;
Zhou, Shuxue ;
Yang, Shu ;
Wu, Limin .
ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (07) :1035-1041
[7]   Transparent superhydrophobic/superhydrophilic coatings for self-cleaning and anti-fogging [J].
Chen, Yu ;
Zhang, Yabin ;
Shi, Lei ;
Li, Jing ;
Xin, Yan ;
Yang, Tingting ;
Guo, Zhiguang .
APPLIED PHYSICS LETTERS, 2012, 101 (03)
[8]   Influence of mechanical properties on the nanoscratch behaviour of hard nanocomposite TiN/Si3N4 coatings on Si [J].
D Beake, B ;
Vishnyakov, VM ;
Valizadeh, R ;
Colligon, JS .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2006, 39 (07) :1392-1397
[9]   Nanocomposite coating superhydrophobicity recovery after prolonged high-impact simulated rain [J].
Davis, Alexander ;
Yeong, Yong Han ;
Steele, Adam ;
Loth, Eric ;
Bayer, Ilker S. .
RSC ADVANCES, 2014, 4 (88) :47222-47226
[10]   Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating [J].
Deng, Xu ;
Mammen, Lena ;
Butt, Hans-Juergen ;
Vollmer, Doris .
SCIENCE, 2012, 335 (6064) :67-70