On the Phosphite-Mediated Synthesis of Dithiafulvenes and π-Extended Tetrathiafulvalenes

被引：10

作者：

Schou, Simon Stubbe ^{[1
]}

Parker, Christian Richard ^{[1
]}

Lincke, Kasper ^{[1
]}

Jennum, Karsten ^{[1
]}

Vibenholt, Johan ^{[1
]}

Kadziola, Anders ^{[1
]}

Nielsen, Mogens Brondsted ^{[1
]}

机构：

[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen O, Denmark

来源：

SYNLETT | 2013年 / 24卷 / 02期

关键词：

cruciform; heterocycles; phosphite; sulfur; tetrathiafulvalene; TRIALKYL PHOSPHITES; PHTHALIC-ANHYDRIDE; BIPHTHALYL; CONVERSION; ANALOGS; TTF;

D O I：

10.1055/s-0032-1317921

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of pi-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.

引用

页码：231 / 235

页数：5

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