Chitosan/montmorillonite composites for fast removal of methylene blue from aqueous solutions

被引：76
|
作者：
El-Kousy, Salah M. [1 ]
El-Shorbagy, Hadeel G. [2 ]
Abd El-Ghaffar, M. A. [3 ]
机构：
[1] Menoufia Univ, Fac Sci, Chem Dept, Menoufia, Egypt
[2] Al Menoufia Water & Wastewater Co, Water Qual Audit Dept, Menoufia, Egypt
[3] Natl Res Ctr, Dept Polymers & Pigments, Cairo, Egypt
来源：
MATERIALS CHEMISTRY AND PHYSICS | 2020年 / 254卷
关键词：
Chitosan; Nano-montmorillonite; Composite; MB; Adsorption; MUSSEL-INSPIRED CHEMISTRY; FUNCTIONALIZED CARBON NANOTUBES; REACTIVE BLACK 5; FACILE PREPARATION; ADSORPTIVE REMOVAL; MAGNETIC CHITOSAN; DYE REMOVAL; MONTMORILLONITE; COMBINATION; WATER;
D O I：
10.1016/j.matchemphys.2020.123236
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
New modified chitosan nano-montmorillonite composites were synthesized for efficient removal of Methylene Blue (MB) pollutant. The composites' structure and morphology were confirmed by H-1 NMR, FTIR, TGA, SEM, XRD, XPS, water regain, stability in acidic medium, and pH(pzc). Factors influencing dye adsorption; nano-montmorillonite ratio, initial dye concentration, composite dose, pH, temperature, contact time, and desorption were investigated. The new modified composites showed very fast adsorption performance and equilibrium occurred after 8 min with adsorption capacity 248.9, 276.03, 204.39, and 180 mg/g for R0, RI, RII, and RIII respectively. MB adsorption is a multilayer process preceded via electrostatic attraction in alkaline medium and/or cation exchange in acidic medium. Adsorption data is well-fitting to Freundlich isotherm and pseudo-second-order kinetics. The composites prepared showed high desorption ability amounting to 77.13, 84.28, 88.47, and 97% for R0, RI, RII, and RIII respectively by using 0.5 M HCl eluent.
引用
收藏
页数：12
相关论文
共 50 条
  • [1] Agar/maltodextrin/poly(vinyl alcohol) walled montmorillonite composites for removal of methylene blue from aqueous solutions
    Thuong Thi Nguyen
    Bich Ngoc Hoang
    Thuan Van Tran
    Dai Van Nguyen
    Trinh, Duy Nguyen
    Vo, Dai-Viet N.
    SURFACES AND INTERFACES, 2021, 26
  • [2] Removal of methylene blue from water with montmorillonite nanosheets/chitosan hydrogels as adsorbent
    Kang, Shichang
    Zhao, Yunliang
    Wang, Wei
    Zhang, Tingting
    Chen, Tianxing
    Yi, Hao
    Rao, Feng
    Song, Shaoxian
    APPLIED SURFACE SCIENCE, 2018, 448 : 203 - 211
  • [3] REMOVAL PROPERTIES OF METHYLENE BLUE FROM AQUEOUS SOLUTIONS BY ORGANOMODIFIED MONTMORILLONITE: ISOTHERM, THERMODYNAMICS AND KINETIC STUDIES
    Boudjemaa, Soufiane
    Zidelkheir, Belkacem
    REVUE ROUMAINE DE CHIMIE, 2020, 65 (05) : 499 - 508
  • [4] Microwave Enhanced Synthesis of Sulfonated Chitosan-Montmorillonite for Effective Removal of Methylene Blue
    Mubarak, Nur Shazwani Abdul
    Bahrudin, N. N.
    Jawad, Ali H.
    Hameed, B. H.
    Sabar, S.
    JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2021, 29 (12) : 4027 - 4039
  • [5] Cationic Dye (Methylene Blue) Removal from Aqueous Solution by Montmorillonite
    Fil, Baybars Ali
    Ozmetin, Cengiz
    Korkmaz, Mustafa
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2012, 33 (10) : 3184 - 3190
  • [6] Removal of methylene blue from aqueous solution using chitosan-g-poly (acrylic acid)/montmorillonite superadsorbent nanocomposite
    Wang, Li
    Zhang, Junping
    Wang, Aiqin
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 322 (1-3) : 47 - 53
  • [7] Removal of Methylene Blue from Aqueous Solutions Using Poly(vinyl alcohol)/Montmorillonite Nanocomposite Hydrogels: Taguchi Optimization
    Roufegari-Nejhad, Ehsan
    Sirousazar, Mohammad
    Abbasi-Chiyaneh, Vahid
    Kheiri, Farshad
    JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2019, 27 (10) : 2239 - 2249
  • [8] Preparation of sulfonated chitosan for enhanced adsorption of methylene blue from aqueous solution
    Sabar, S.
    Aziz, H. Abdul
    Yusof, N. H.
    Subramaniam, S.
    Foo, K. Y.
    Wilson, L. D.
    Lee, H. K.
    REACTIVE & FUNCTIONAL POLYMERS, 2020, 151
  • [9] Adsorption of methylene blue onto chitosan?montmorillonite/ polyaniline nanocomposite
    Minisy, Islam M.
    Salahuddin, Nehal A.
    Ayad, Mohamad M.
    APPLIED CLAY SCIENCE, 2021, 203
  • [10] Preparation and Characterization of Iminated Polyacrylonitrile for the Removal of Methylene Blue from Aqueous Solutions
    Abu-Saied, M. A.
    Abdel-Halim, E. S.
    Fouda, Moustafa M. G.
    Al-Deyab, Salem S.
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2013, 8 (04): : 5121 - 5135
12345