Dynamic modeling of the morphology of multiphase waterborne polymer particles

被引:13
作者
Akhmatskaya, Elena [1 ]
Asua, Jose M. [2 ,3 ]
机构
[1] Basque Ctr Appl Math BCAM, Bilbao 48009, Basque Country, Spain
[2] Univ Basque Country UPV EHU, POLYMAT, Donostia San Sebastian 20018, Spain
[3] Univ Basque Country UPV EHU, Grp Ingn Quim, Dept Quim Aplicada, Fac Ciencias Quim, Donostia San Sebastian 20018, Spain
关键词
Waterborne multiphase particles; Dynamic modeling; Development of particle morphology; Polymer-polymer hybrid; Polymer-polymer-inorganic hybrid; COMPOSITE LATEX-PARTICLES; MINIEMULSION POLYMERIZATION; EMULSION POLYMERIZATION; INORGANIC PARTICLES; SURFACE-TENSION; DIFFUSION; ENCAPSULATION; SIMULATION; MONOMER; NUCLEATION;
D O I
10.1007/s00396-012-2740-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multiphase waterborne polymer particles provide advantages in more demanding applications, and their performance depends on particle morphology. Currently, no dynamic model for the prediction of the development of the morphology of multiphase latex particles is available. In this work, a model was developed for the prediction of the dynamic development of the morphology of multiphase waterborne systems, such as polymer-polymer and polymer-polymer-inorganic hybrids.
引用
收藏
页码:87 / 98
页数:12
相关论文
共 72 条
[1]   Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer [J].
Akhmatskaya, Elena ;
Asua, Jose M. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (07) :1383-1393
[2]   MOLECULAR-WEIGHT DISTRIBUTIONS IN THE MINIEMULSION POLYMERIZATION OF STYRENE INITIATED BY OIL-SOLUBLE INITIATORS [J].
ALDUNCIN, JA ;
ASUA, JM .
POLYMER, 1994, 35 (17) :3758-3765
[3]  
Asua J.M., 1997, Polymeric dispersions: principles and applications, DOI [10.1007/978-94-011-5512-0, DOI 10.1007/978-94-011-5512-0]
[5]   Particles as surfactants - similarities and differences [J].
Binks, BP .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (1-2) :21-41
[6]   Organic-inorganic nanostructured colloids [J].
Bourgeat-Lami, E .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2002, 2 (01) :1-24
[7]   Emulsion polymerization in the presence of colloidal silica particles - Application to the reinforcement of poly(ethyl acrylate) films [J].
Bourgeat-Lami, E ;
Espiard, P ;
Guyot, A ;
Gauthier, C ;
David, L ;
Vigier, G .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1996, 242 :105-122
[8]   Silica/polyamide nanocomposite synthesis via an original double emulsification process in miniemulsion [J].
Boutti, S ;
Bourgeat-Lami, E ;
Zydowicz, N .
MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (23) :1860-1865
[9]   Semiconductor nanocrystals as fluorescent biological labels [J].
Bruchez, M ;
Moronne, M ;
Gin, P ;
Weiss, S ;
Alivisatos, AP .
SCIENCE, 1998, 281 (5385) :2013-2016
[10]   Pickering stabilized miniemulsion polymerization: Preparation of clay armored latexes [J].
Cauvin, S ;
Colver, PJ ;
Bon, SAF .
MACROMOLECULES, 2005, 38 (19) :7887-7889