High-Speed Coating of Primer Layer for Li-Ion Battery Electrodes by Using Slot-Die Coating

被引:24
作者
Diehm, Ralf [1 ]
Mueller, Marcus [2 ]
Burger, David [1 ]
Kumberg, Jana [1 ]
Spiegel, Sandro [1 ]
Bauer, Werner [2 ]
Scharfer, Philip [1 ]
Schabel, Wilhelm [1 ]
机构
[1] Karlsruhe Inst Technol KIT, Inst Thermal Proc Engn, Thin Film Technol, D-76131 Karlsruhe, Germany
[2] Karlsruhe Inst Technol KIT, Inst Appl Mat Energy Storage Syst ESS, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
关键词
carbon coating; coating window; Li-ions; primer layers; slot-die coating; vacuum box; LOW-FLOW LIMIT; CURRENT COLLECTOR; LITHIUM; PERFORMANCE;
D O I
10.1002/ente.202000259
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A reduction of the inactive components can increase the energy density and reduce production cost of Li-ion batteries. But an effective reduction of the binder amount also negatively affects the adhesion of the electrode. Herein, slot-die coating of a primer layer for Li-ion anodes is investigated. It is shown that the use of a primer layer with only 0.3 g m(-2)can increase the adhesive force by the factor of 5 as well as the cell performance for anodes with low binder content. The process limits for a stable, defect-free primer coating are investigated at coating speeds of up to 550 m min(-1). The limits coincide both for a setup without vacuum box and with vacuum box with theory-based equations. By using a vacuum box, the minimum wet film thickness can be reduced by half.
引用
收藏
页数:8
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