Cooperative self-assembly of porphyrins with polymers possessing bioactive functions

被引：46
|
作者：
Zhao, Lizhi [1 ]
Qu, Rui [2 ]
Li, Ang [2 ]
Ma, Rujiang [2 ]
Shi, Linqi [2 ]
机构：
[1] Tianjin Polytech Univ, Sch Mat Sci & Engn, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China
[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, State Key Lab Med Chem Biol, Key Lab Funct Polymer Mat,Minist Educ,Inst Polyme, Tianjin 300071, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 93期
基金：
中国国家自然科学基金;
关键词：
POLYION COMPLEX MICELLES; DIATOMIC-MOLECULES O-2; PHOTODYNAMIC THERAPY; AQUEOUS-SOLUTION; SUPRAMOLECULAR COMPLEX; BLOCK-COPOLYMER; ENERGY-TRANSFER; DENDRIMER PHTHALOCYANINE; ARTIFICIAL PEROXIDASE; MAGNESIUM PORPHYRIN;
D O I：
10.1039/c6cc05449h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Natural porphyrin derivatives possess many interesting functions in biological systems. They are integrated into proteins that are essential for biological activities. Many efforts have been dedicated to mimic the microenvironment and augment the function of porphyrin/protein scaffolds. To achieve such goals, self-assembly has become one of the popular methods to construct porphyrin/protein-mimicking materials owing to its various choices of building blocks and a simple preparation process over chemical modification. Desirable characteristics of building blocks for protein mimicking include high molecular weight, predictable conformations in solution, and appropriate functional residuals. With these aims in mind, polymers are ideal candidates due to their multiple-level hierarchies derived from their chemical and spatial structures. In this review, design strategies for the cooperative self-assembly of porphyrins with polymers and the main efforts towards the implementation of porphyrin/polymer assembly for biomimetic composites with bioactive functions will be addressed.
引用
收藏
页码：13543 / 13555
页数：13
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