Flower-like NiCo2O4 Microstructures as Promising Anode Material for High Performance Lithium-Ion Batteries: Facile Synthesis and its Lithium Storage Properties

被引:15
作者
Sun, Yuanwei [1 ]
Zuo, Xintao [1 ]
Xu, Dan [1 ]
Sun, Dezhi [1 ]
Zhang, Xianxi [1 ]
Zeng, Suyuan [1 ]
机构
[1] Liaocheng Univ, Sch Chem & Chem Engn, Shandong Prov Key Lab Chem Energy Storage & Novel, Liaocheng 252059, Peoples R China
来源
CHEMISTRYSELECT | 2016年 / 1卷 / 16期
基金
中国国家自然科学基金;
关键词
anode material; flower-like; lithium ion battery; NiCo2O4 simple method; ENHANCED ELECTROCHEMICAL PERFORMANCE; HOLLOW SPHERES; CAPACITY; MNCO2O4; NANOPARTICLES; MICROSPHERES; ELECTRODE; ZNCO2O4; NANOCOMPOSITES; CYCLABILITY;
D O I
10.1002/slct.201601147
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Flower-like NiCo2O4 microstructures were prepared through thermal decomposition of the Ni-Co- intermediate. The as-prepared NiCo2O4 microstructures are proved to be mesoporous according to the N-2 adsorption-desorption experiments, which is beneficial for the improvement of the electrochemical performance. The as-prepared NiCo2O4 microstructures exhibit excellent cycling stability (1128 mA h g(-1) at a current density of 1000 mA g(-1), after 330 cycles) when being used as the anode materials for lithium-ion batteries (LIBs). Even being discharged a high current density of 5000 mA g(-1), the discharge capacity can still reach 948.1 mA h g(-1). The superior electrochemical properties can be attributed to the unique 3D structure, structural stability and porous structure, all of which can effectively increase the contact area of the electrode-electrolyte and improve the stability of anode.
引用
收藏
页码:5129 / 5136
页数:8
相关论文
共 59 条
  • [1] Building better batteries
    Armand, M.
    Tarascon, J. -M.
    [J]. NATURE, 2008, 451 (7179) : 652 - 657
  • [2] Microwave synthesis and effect of CTAB on ferromagnetic properties of NiO, Co3O4 and NiCo2O4 nanostructures
    Babu, G. Anandha
    Ravi, G.
    Hayakawa, Y.
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2015, 119 (01): : 219 - 232
  • [3] Unusual Formation of ZnCo2O4 3D Hierarchical Twin Microspheres as a High-Rate and Ultralong-Life Lithium-Ion Battery Anode Material
    Bai, Jing
    Li, Xiaogang
    Liu, Guangzeng
    Qian, Yitai
    Xiong, Shenglin
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (20) : 3012 - 3020
  • [4] Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity
    Balaya, P
    Li, H
    Kienle, L
    Maier, J
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (08) : 621 - 625
  • [5] Nanomaterials for rechargeable lithium batteries
    Bruce, Peter G.
    Scrosati, Bruno
    Tarascon, Jean-Marie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
  • [6] Robust growth of herringbone carbon nanofibers on layered double hydroxide derived catalysts and their applications as anodes for Li-ion batteries
    Cheng, Xin-Bing
    Tian, Gui-Li
    Liu, Xiao-Fei
    Nie, Jing-Qi
    Zhao, Meng-Qiang
    Huang, Jia-Qi
    Zhu, Wancheng
    Hu, Ling
    Zhang, Qiang
    Wei, Fei
    [J]. CARBON, 2013, 62 : 393 - 404
  • [7] Anodic electrochemical performances of MgCo2O4 synthesized by oxalate decomposition method and electrospinning technique for Li-ion battery application
    Darbar, Devendrasinh
    Reddy, M. V.
    Sundarrajan, S.
    Pattabiraman, R.
    Ramakrishna, S.
    Chowdari, B. V. R.
    [J]. MATERIALS RESEARCH BULLETIN, 2016, 73 : 369 - 376
  • [8] De Chlalvo M. R. Gennero, 1993, ELECTROCHIM ACTA, V15, P2247
  • [9] A NiCo2O4 nanosheet-mesoporous carbon composite electrode for enhanced reversible lithium storage
    Fan, Zhaoyang
    Wang, Baorui
    Xi, Yingxin
    Xu, Xin
    Li, Mingyan
    Li, Jun
    Coxon, Paul
    Cheng, Shaodong
    Gao, Guoxin
    Xiao, Chunhui
    Yang, Guang
    Xi, Kai
    Ding, Shujiang
    Kumar, R. Vasant
    [J]. CARBON, 2016, 99 : 633 - 641
  • [10] Citrate-Assisted Growth of NiCo2O4 Nanosheets on Reduced Graphene Oxide for Highly Reversible Lithium Storage
    Gao, Guoxin
    Wu, Hao Bin
    Lou, Xiong Wen
    [J]. ADVANCED ENERGY MATERIALS, 2014, 4 (14)