Structure and activity of Candida antarctica lipase B in ionic liquids

被引：129
|
作者：
van Rantwijk, F
Secundo, F
Sheldon, RA
机构：
[1] CNR, Ist Chim Riconoscimento Mol, I-20133 Milan, Italy
[2] Delft Univ Technol, Lab Biocatalysis & Organ Chem, NL-2628 BL Delft, Netherlands
来源：
GREEN CHEMISTRY | 2006年 / 8卷 / 03期
关键词：
D O I：
10.1039/b513062j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effects of ionic liquid media on the activity of Candida antarctica lipase B in a simple transesterification reaction were studied. In ionic liquids containing dicyanimide, alkylsulfate, nitrate and lactate anions, which dissolved CaLB, the reaction was at least ten times slower than in [BMIm][BF4]. Only [Et3MeN][MeSO4] was an exception, as dissolved CaLB maintained its activity in this solvent. A cross-linked enzyme aggregate of CaLB was twice as active in [BMIm][dca] as in tert-butyl alcohol, whereas the free enzyme was irreversibly deactivated in this latter ionic liquid.
引用
收藏
页码：282 / 286
页数：5
相关论文
共 50 条
  • [21] Buffer-mediated activation of Candida antarctica lipase B dissolved in hydroxyl-functionalized ionic liquids
    Ou, Guangnan
    Yang, Jing
    He, Biyan
    Yuan, Youzhu
    JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2011, 68 (01) : 66 - 70
  • [22] Chemo-enzymatic Baeyer-Villiger oxidation in the presence of Candida antarctica lipase B and ionic liquids
    Drozdz, Agnieszka
    Erfurt, Karol
    Bielas, Rafal
    Chrobok, Anna
    NEW JOURNAL OF CHEMISTRY, 2015, 39 (02) : 1315 - 1321
  • [23] The effect of ionic liquid media on activity, selectivity and stability of Candida antarctica lipase B in transesterification reactions
    De Los Rios, Antonia P.
    Hernandez-Fernandez, Francisco J.
    Martinez, Francisco A.
    Rubio, Manuel
    Villora, Gloria
    BIOCATALYSIS AND BIOTRANSFORMATION, 2007, 25 (2-4) : 151 - 156
  • [24] Optimization of (R,S)-1-phenylethanol kinetic resolution over Candida antarctica lipase B in ionic liquids
    Habulin, Maja
    Knez, Zeljko
    JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2009, 58 (1-4) : 24 - 28
  • [25] Efficient asymmetric acylation of (R,S)-1-trimethylsilylethanol catalyzed by Candida antarctica lipase B in ionic liquids
    Lou, Wen-Yong
    Zong, Min-Hua
    Wu, Hong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U563 - U563
  • [26] Enhancing the Catalytic Performance of Candida antarctica Lipase B by Immobilization onto the Ionic Liquids Modified SBA-15
    Zhong, Nanjing
    Li, Yue
    Cai, Chunsheng
    Gao, Yongqing
    Liu, Ning
    Liu, Guoqin
    Tan, Wenying
    Zeng, Yaoying
    EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2018, 120 (04)
  • [27] Screening of solvents for favoring hydrolytic activity of Candida antarctica Lipase B
    Zieniuk, Bartlomiej
    Fabiszewska, Agata
    Bialecka-Florjanczyk, Ewa
    BIOPROCESS AND BIOSYSTEMS ENGINEERING, 2020, 43 (04) : 605 - 613
  • [28] Screening of solvents for favoring hydrolytic activity of Candida antarctica Lipase B
    Bartłomiej Zieniuk
    Agata Fabiszewska
    Ewa Białecka-Florjańczyk
    Bioprocess and Biosystems Engineering, 2020, 43 : 605 - 613
  • [29] Conformation and activity of lipase B from Candida antarctica in bicontinuous microemulsions
    Subinya, Mireia
    Steudle, Anne K.
    Jurkowski, Tomasz P.
    Stubenrauch, Cosima
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2015, 131 : 108 - 114
  • [30] Enhancement of Candida antarctica lipase B enantioselectivity and activity in organic solvents
    Parker, MC
    Brown, SA
    Robertson, L
    Turner, NJ
    CHEMICAL COMMUNICATIONS, 1998, (20) : 2247 - 2248
12345