Ni-Au alloy nanoparticles as a high performance heterogeneous catalyst for hydrogenation of aromatic nitro compounds

被引:20
作者
Lang, Leiming [1 ,2 ]
Pan, Zhaorui [1 ]
Yan, Jun [1 ]
机构
[1] Nanjing Xiaozhuang Univ, Lab Adv Funct Mat Nanjing, Nanjing 211171, Jiangsu, Peoples R China
[2] Nanjing Univ, State Key Lab Analyt Chem Life Sci, Nanjing 210093, Jiangsu, Peoples R China
关键词
Ni-Au; Metals and alloys; Hydrogenation; Aromatic nitro compounds; Catalysis; CHEMOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; GOLD; METAL; REDUCTION; EFFICIENT; AZO;
D O I
10.1016/j.jallcom.2019.03.323
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Selective hydrogenation of nitro compounds requires highly active and less expensive materials as a heterogeneous catalyst. As a good candidate, the Ni-Au alloy nanoparticles (NPs) have been synthesized by simple in-situ reduction method, which was loaded to the active carbon with 10 wt % loading amount. The Ni-Au/C catalyst shows superior catalytic performance for hydrogenation of nitro compounds with 100% conversion and selectivity without any by-products, which also indicates good recycle performance for several times use. The prepared catalyst not only reduces the usage amount of noble metal, but also keeps the high catalytic activity, which is a promising catalyst for industry applications. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:286 / 290
页数:5
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