Gold(III) Olefin Complexes

被引：71
|
作者：
Savjani, Nicky [1 ]
Rosca, Dragos-Adrian [1 ]
Schormann, Mark [1 ]
Bochmann, Manfred [1 ]
机构：
[1] Univ E Anglia, Wolfson Mat & Catalysis Ctr, Sch Chem, Norwich NR4 7TJ, Norfolk, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 03期
关键词：
aurophilic bonds; coordination chemistry; ethylene; gold; homogeneous catalysis; NUCLEAR-MAGNETIC-RESONANCE; GOLD CATALYSIS; HOMOGENEOUS CATALYSIS; CRYSTAL-STRUCTURE; ORGANIC TRANSFORMATIONS; AUROPHILIC INTERACTIONS; MOLECULAR STRUCTURE; ZEISES SALT; HYDROGENATION; ETHYLENE;
D O I：
10.1002/anie.201208356
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for AuIII-Ag interactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：874 / 877
页数：4
相关论文
共 50 条
  • [1] OLEFIN GOLD COMPLEXES .8. CYCLOOCTATETRAENE GOLD CHLORIDE COMPLEXES
    TAUCHNER, P
    HUTTEL, R
    CHEMISCHE BERICHTE-RECUEIL, 1974, 107 (12): : 3761 - 3770
  • [2] Gold(iii) complexes
    Blons, Charlie
    Amgoune, Abderrahmane
    Bourissou, Didier
    DALTON TRANSACTIONS, 2018, 47 (31) : 10388 - 10393
  • [3] OLEFIN GOLD COMPLEXES .7. HEXAMETHYL DEWARBENZENE AND GOLD-(III)-CHLORIDE - CARBONIUM-IONS AS INTERMEDIATES IN CHLORINATION OF OLEFINS WITH GOLD-(III)-CHLORIDE
    HUTTEL, R
    TAUCHNER, P
    FORKL, H
    CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (01): : 1 - &
  • [4] OLEFIN-GOLD COMPLEXES .6. MIXED GOLD(I)-GOLD(3) COMPLEXES VIA OLEFINS
    HUTTEL, R
    REINHEIM.H
    NOWAK, K
    CHEMISCHE BERICHTE-RECUEIL, 1968, 101 (11): : 3761 - &
  • [5] Gold(III) π-Allyl Complexes
    Rodriguez, Jessica
    Szaloki, Gyoergy
    Carrizo, E. Daiann Sosa
    Saffon-Merceron, Nathalie
    Miqueu, Karinne
    Bourissou, Didier
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (04) : 1511 - 1515
  • [6] (TETRAHYDROTHIOPHENE)GOLD(I) OR GOLD(III) COMPLEXES
    USON, R
    LAGUNA, A
    LAGUNA, M
    BRIGGS, DA
    MURRAY, HH
    FACKLER, JP
    INORGANIC SYNTHESES, 1989, 26 : 85 - 91
  • [7] CHELATE COMPLEXES OF GOLD(III)
    DAR, MA
    PARISH, RV
    MCAULIFFE, CA
    BRAMHILL, AS
    HYPERFINE INTERACTIONS, 1988, 40 (1-4): : 323 - 326
  • [8] GOLD(III) COMPLEXES OF DITHIOMALONAMIDES
    PELLACANI, GC
    INORGANICA CHIMICA ACTA, 1975, 12 (01) : L3 - L4
  • [9] PENTACHLOROPHENYL COMPLEXES OF GOLD(I) AND GOLD(III)
    USON, R
    LAGUNA, A
    DELAORDEN, MU
    ARRESE, ML
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1984, 14 (03): : 369 - 381
  • [10] Selective olefin epoxidation catalyzed by Ga(III) complexes
    Goldsmith, Christian R.
    Jiang, Wenchan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
12345