Development of Intramolecular Vicinal Diamination of Alkenes: From Palladium to Bromine Catalysis

被引：155

作者：

Muniz, Kilian ^{[1
,2
]}

Martinez, Claudio ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, E-43007 Tarragona, Spain

[2] Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 06期

关键词：

CU(I)-CATALYZED REGIOSELECTIVE DIAMINATION; METAL-FREE DIAMINATION; CONJUGATED DIENES; ASYMMETRIC DIAMINATION; TERMINAL OLEFINS; PD(0)-CATALYZED DIAMINATION; INTERMOLECULAR DIAMINATION; OXIDATIVE DIAMINATION; BOND FORMATION; COPPER;

D O I：

10.1021/jo302472w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium catalysis has been instrumental in the development of the intramolecular diamination of alkenes. Reagent combinations of a palladium catalyst and iodosobenzene diacetate or copper(II) salts, respectively, represent the broad applicability and mechanistic variation. Recent work has established alternative copper and bromine catalysts. The occupation with this reaction has also contributed to the development of high oxidation state metal catalysis in alkene difiinctionalization and significantly broadened the spectrum of Pd-catalyzed C-N bond-forming reactions in general.

引用

页码：2168 / 2174

页数：7

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