A Phosphorescent Ir(III) Complex for Selective Fluoride Ion Sensing with a High Signal-to-Noise Ratio

被引：139

作者：

You, Youngmin ^{[1
]}

Park, Soo Young ^{[1
]}

机构：

[1] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 151744, South Korea

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 20期

关键词：

D O I：

10.1002/adma.200702667

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly phosphorescent Ir(III) complex, containing a dimesitylboryl group in its coordinative phenylpyridine ligand, exhibited a phosphorescence colorimetric and ratiometric fluoride ion-selective sensing behavior and enabled facile signal purification through time-gated acquisition. Poly(methylmethacrylate) films doped with the Ir(III) complex were used to successfully detect fluoride ion in aqueous media.

引用

页码：3820 / +

页数：8

共 66 条

[1] Dibenzophosphaborin:: A hetero-π-conjugated molecule with fluorescent properties based on intramolecular charge transfer between phosphorus and boron atoms [J].

Agou, T ;

Kobayashi, J ;

Kawashima, T .

ORGANIC LETTERS, 2005, 7 (20) :4373-4376

[2] Tuning of the optical properties and Lewis acidity of dibenzopnictogenaborins by modification on bridging main group elements [J].

Agou, Tomohiro ;

Kobayashi, Junji ;

Kawashima, Takayuki .

INORGANIC CHEMISTRY, 2006, 45 (22) :9137-9144

[3] Synthesis and structural characterisation of the first bis(bora)calixarene:: a selective, bidentate, fluorescent fluoride sensor [J].

Arimori, S ;

Davidson, MG ;

Fyles, TM ;

Hibbert, TG ;

James, TD ;

Kociok-Köhn, GI .

CHEMICAL COMMUNICATIONS, 2004, (14) :1640-1641

[4] Charge-transfer emission involving three-coordinate organoboron: V-shape versus U-Shape and impact of the spacer on dual emission and fluorescent sensing [J].

Bai, Dong-Ren ;

Liu, Xiang-Yang ;

Wang, Suning .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (20) :5713-5723

[5] Dipyrrolylquinoxalines: Efficient sensors for fluoride anion in organic solution [J].

Black, CB ;

Andrioletti, B ;

Try, AC ;

Ruiperez, C ;

Sessler, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (44) :10438-10439

[6] Nature of urea-fluoride interaction:: Incipient and definitive proton transfer [J].

Boiocchi, M ;

Del Boca, L ;

Gómez, DE ;

Fabbrizzi, L ;

Licchelli, M ;

Monzani, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (50) :16507-16514

[7] Selective electrochemical detection of hydrogen fluoride by ambiphilic ferrocene derivatives [J].

Bresner, C ;

Aldridge, S ;

Fallis, IA ;

Jones, C ;

Ooi, LL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) :3606-3609

[8] Bis[di-n-alkyl(fluoro)stannyl]methanes, (R2FSn)2CH2 (R = n-octyl, n-dodecyl):: Stable fluoride-selective carriers [J].

Chaniotakis, N ;

Jurkschat, K ;

Müller, D ;

Perdikaki, K ;

Reeske, G .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (11) :2283-2288

[9] A calix[4]imidazolium[2]pyridine as an anion receptor [J].

Chellappan, K ;

Singh, NJ ;

Hwang, IC ;

Lee, JW ;

Kim, KS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (19) :2899-2903

[10] Fluoride ion capture from water with a cationic borane [J].

Chiu, Ching-Wen ;

Gabbai, Francois P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (44) :14248-14249

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