Performance of four artificial chlorin-type sensitizers with different stereostructures in dye-sensitized solar cells

被引：16

作者：

Liu, Xiujun ^{[1
]}

Li, Chengjie ^{[1
]}

Peng, Xiao ^{[1
]}

Zhou, Yongzhu ^{[1
]}

Zeng, Zhe ^{[1
]}

Li, Yuanchao ^{[1
]}

Zhang, Tianyi ^{[1
]}

Zhang, Bao ^{[1
]}

Dong, Yi ^{[2
]}

Sun, Dongming ^{[3
]}

Cheng, Ping ^{[3
]}

Feng, Yaqing ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Nankai QU, Tianjin 300072, Peoples R China

[2] Univ Saarland, D-66123 Saarbrucken, Germany

[3] Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China

来源：

DYES AND PIGMENTS | 2013年 / 98卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Porphyrin; Chlorin; 1,3-Dipolar cycloaddition reaction; Dye-sensitized solar cell; Absorption spectra in TiO2 films; Photovoltaic performance; 1,3-DIPOLAR CYCLOADDITION REACTIONS; EFFICIENT PORPHYRIN SENSITIZERS; POWER-CONVERSION EFFICIENCY; BAND-GAP CHROMOPHORES; HIGHLY EFFICIENT; FUSED CHLORINS; ORGANIC-DYES; COUMARIN DYES; CHLOROPHYLL; DERIVATIVES;

D O I：

10.1016/j.dyepig.2013.01.013

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Four artificial chlorin-type sensitizers have been prepared and their photovoltaic performance in dye-sensitized solar cells has been evaluated. It was found that the photovoltaic performance increased with growing absorption intensity of the Q band in a TiO2 film. This result indicates the contribution of intrinsic enhanced absorption properties of chlorins in the Q band regions on the improvement of the overall photovoltaic performance in DSSCs. On the other hand, their capability of solar energy conversion also exhibits close relationship with the geometry of the four sensitizers, in which the orientation of a sterically demanding 2,6-dichlorophenyl group towards either the 5- or 15-position (the anchor group is at the 20-position) gives higher solar energy-to-electricity conversion efficiency. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：181 / 189

页数：9

共 74 条

[1] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].

ADLER, AD ;

LONGO, FR ;

FINARELLI, JD ;

GOLDMACH.J ;

ASSOUR, J ;

KORSAKOF.L .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) :476-+

[2] Bio-photovoltaic conversion device using chlorine-e6 derived from chlorophyll from Spirulina adsorbed on a nanocrystalline TiO2 film electrode [J].

Amao, Y ;

Komori, T .

BIOSENSORS & BIOELECTRONICS, 2004, 19 (08) :843-847

[3]

[Anonymous], J MAT CHEM

[4] DFT/TD-DFT molecular design of porphyrin analogues for use in dye-sensitized solar cells [J].

Balanay, Mannix P. ;

Kim, Dong Hee .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (33) :5121-5127

[5] A method for concurrent diazomethane synthesis and substrate methylation in a 96-sample format [J].

Barkawi, Lana S. ;

Cohen, Jerry D. .

NATURE PROTOCOLS, 2010, 5 (10) :1619-1626

[6] Synthetic routes to multiporphyrin arrays [J].

Burrell, AK ;

Officer, DL ;

Plieger, PG ;

Reid, DCW .

CHEMICAL REVIEWS, 2001, 101 (09) :2751-2796

[7] Highly efficient porphyrin sensitizers for dye-sensitized solar cells [J].

Campbell, Wayne M. ;

Jolley, Kenneth W. ;

Wagner, Pawel ;

Wagner, Klaudia ;

Walsh, Penny J. ;

Gordon, Keith C. ;

Schmidt-Mende, Lukas ;

Nazeeruddin, Mohammad K. ;

Wang, Qing ;

Gratzel, Michael ;

Officer, David L. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (32) :11760-11762

[8] CHROMATOGRAPHY OF CHLOROPHYLLS AND BACTERIOCHLOROPHYLLS [J].

CAVALEIRO, JAS ;

SMITH, KM .

TALANTA, 1986, 33 (12) :963-971

[9] A strategy to design highly efficient porphyrin sensitizers for dye-sensitized solar cells [J].

Chang, Yu-Cheng ;

Wang, Chin-Li ;

Pan, Tsung-Yu ;

Hong, Shang-Hao ;

Lan, Chi-Ming ;

Kuo, Hshin-Hui ;

Lo, Chen-Fu ;

Hsu, Hung-Yu ;

Lin, Ching-Yao ;

Diau, Eric Wei-Guang .

CHEMICAL COMMUNICATIONS, 2011, 47 (31) :8910-8912

[10] Organic dyes incorporating the cyclopentadithiophene moiety for efficient dye-sensitized solar cells [J].

Cheng, Xiaobing ;

Sun, Siyuan ;

Liang, Mao ;

Shi, Yongbo ;

Sun, Zhe ;

Xue, Song .

DYES AND PIGMENTS, 2012, 92 (03) :1292-1299

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