The functionalized TiO2 with poly(methyl methacrylate) (TiO2-PMMA) was prepared by atom transfer radical polymerization (ATRP), and its reinforcement for epoxy composites was studied. The functionalized TiO2 was characterized by Fourier transform infrared (FT-IR), Thermal gravimetric analysis (TGA) and H-1 nuclear magnetic resonance (NMR). The properties of nanocomposites were measured by impact testing, bending experiment and Scanning electron microscopy (SEM). Because of the grafting of PMMA and the higher interaction between TiO2-PMMA and epoxy matrix, the composites exhibited the enhancement of mechanical properties at lower content. As the functionalized TiO2 content is 0.5 wt%, the impact strength and bending strength of composite increased nearly 142% and 37%, respectively, compared to the neat epoxy resin.
机构:
Indian Inst Technol Delhi, Dept Text & Fibre Engn, New Delhi, IndiaIndian Inst Technol Delhi, Dept Text & Fibre Engn, New Delhi, India
Rathi, Ankit
Majumdar, Abhijit
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Indian Inst Technol Delhi, Dept Text & Fibre Engn, New Delhi, IndiaIndian Inst Technol Delhi, Dept Text & Fibre Engn, New Delhi, India
Majumdar, Abhijit
Rathi, Nisha
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Indian Inst Technol Roorkee, Dept Chem Engn, Roorkee, Uttar Pradesh, IndiaIndian Inst Technol Delhi, Dept Text & Fibre Engn, New Delhi, India
Rathi, Nisha
Kumar, Arun
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Indian Inst Technol Roorkee, Dept Met & Mat Engn, Roorkee 247667, Uttar Pradesh, IndiaIndian Inst Technol Delhi, Dept Text & Fibre Engn, New Delhi, India
机构:
Islamic Azad Univ, Dept Chem, North Tehran Branch, Tehran 1667934783, IranIslamic Azad Univ, Dept Chem, North Tehran Branch, Tehran 1667934783, Iran
Faeli, Mohammad
Kiarostami, Vahid
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Islamic Azad Univ, Dept Chem, North Tehran Branch, Tehran 1667934783, IranIslamic Azad Univ, Dept Chem, North Tehran Branch, Tehran 1667934783, Iran
Kiarostami, Vahid
Ahmadi, Seyed Javad
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Nucl Sci & Technol Res Inst, Tehran, IranIslamic Azad Univ, Dept Chem, North Tehran Branch, Tehran 1667934783, Iran