Facile synthesis of amino-functionalised cyclopentadienyl sodium compounds and subsequent formation of rhodium complexes: Proton-deuterium exchange for the sodium salts

被引：25

作者：

McGowan, PC ^{[1
]}

Hart, CE ^{[1
]}

Donnadieu, B ^{[1
]}

Poilblanc, R ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 528卷 / 1-2期

关键词：

exchange; sodium salts; substituted cyclopentadienyls; rhodium;

D O I：

10.1016/S0022-328X(96)06574-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis, isolation and characterisation of sodium salts of amino-substituted cyclopentadienyl compounds was carried out for the first time: these can be made on a large scale and stored easily, thus facilitating easy manipulation and applications. Rhodium derivatives,including Rh(eta(5)-C5H4)CH(CH2CH2)(2)NMe(coe)(2) (coe = cyclo-octene), were synthesised, of which the crystal structure is reported.

引用

页码：191 / 194

页数：4

共 9 条

[1] SYNTHESIS OF ETA-CYCLOPENTADIENYLIDENE-4-IMIDOPROPYLNIOBIUM DERIVATIVES [NB(ETA-SIGMA-C5H4(CH2)3N)CL2] AND [NB(ETA-SIGMA-C5H4(CH2)3N)(PME3)CL2] [J].