A comparative study of m-cresol treated polyaniline and Langmuir Blodgett films

被引：10
作者：
da Silva, JEP
de Torresi, SIC
Temperini, MLA
Gonçalves, D
Oliveira, ON
机构：
[1] Univ Sao Paulo, Dept Quim Fundamental, Inst Quim, BR-05599970 Sao Paulo, Brazil
[2] Univ Sao Paulo, Inst Fis, Sao Carlos, SP, Brazil
来源：
SYNTHETIC METALS | 1999年 / 101卷 / 1-3期
基金：
巴西圣保罗研究基金会;
关键词：
polyaniline; Raman spectroscopy; secondary doping; Langmuir Blodgett films;
D O I：
10.1016/S0379-6779(98)00801-7
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Polyaniline films prepared by Langmuir-Blodgett technique were characterized by X- Ray diffractometry and Raman spectroscopy. The obtained results were compared with those from secondarily doped samples treated with HCSA and m-cresol. When LB films were doped with HCl vapour, the Raman spectrum obtained is different form that of PANI/HCl samples prepared by chemical or electrochemical polymerization, being very close to spectrum of PANI/CSA/m-cresol samples. In LB films a great increase in the intensity of the band correponding to free carriers indicates the important role played by the extended conformation and conductivity.
引用
收藏
页码：691 / 691
页数：1
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