A core-corona hierarchical manganese oxide and its formation by an aqueous soft chemistry mechanism

被引:91
作者
Portehault, David [1 ]
Cassaignon, Sophie [1 ]
Nassif, Nadine [1 ]
Baudrin, Emmanuel [2 ]
Jolivet, Jean-Pierre [1 ]
机构
[1] Univ Paris 06, CNRS, UMR Chim Mat Condensee Paris 7574, F-75005 Paris, France
[2] Univ Picardie Jules Verne, CNRS, UMR 6007, Lab React & Chim Solides, Amiens, France
关键词
crystal growth; layered compounds; manganese; nanostructures; synthesis design;
D O I
10.1002/anie.200800331
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) No template and no organic medium are needed for the low-temperature, one-pot aqueous route to layered manganese oxides with a hierarchical core-corona architecture (see picture). Particle formation occurs by a two-step precipitation process with two different kinetics. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6441 / 6444
页数:4
相关论文
共 31 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   SYNTHESIS AND CHARACTERIZATION OF LAMELLAR MNO2 OBTAINED FROM THERMAL-DECOMPOSITION OF NAMNO4 FOR RECHARGEABLE LITHIUM CELLS [J].
BACH, S ;
PEREIRARAMOS, JP ;
BAFFIER, N .
JOURNAL OF SOLID STATE CHEMISTRY, 1995, 120 (01) :70-73
[3]   Crystalline MnO2 as possible alternatives to amorphous compounds in electrochemical supercapacitors [J].
Brousse, Thierry ;
Toupin, Mathieu ;
Dugas, Romain ;
Athouel, Laurence ;
Crosnier, Olivier ;
Belanger, Daniel .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (12) :A2171-A2180
[4]   Sol-gel synthesis of layered birnessite-type manganese oxides [J].
Ching, S ;
Petrovay, DJ ;
Jorgensen, ML ;
Suib, SL .
INORGANIC CHEMISTRY, 1997, 36 (05) :883-890
[5]   Mesocrystals:: Inorganic superstructures made by highly parallel crystallization and controlled alignment [J].
Cölfen, H ;
Antonietti, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (35) :5576-5591
[6]  
Colfen H., 2005, ANGEW CHEM, V117, P5714
[7]   Controlled synthesis of Ag/TiO2 core-shell nanowires with smooth and bristled surfaces via a one-step solution route [J].
Du, JM ;
Zhang, JL ;
Liu, ZM ;
Han, BX ;
Jiang, T ;
Huang, Y .
LANGMUIR, 2006, 22 (03) :1307-1312
[8]   One-dimensional hierarchical layered KxMnO2 (x<0.3) nanoarchitectures:: Synthesis, characterization, and their magnetic properties [J].
Ge, Jiechao ;
Zhuo, Linhai ;
Yang, Fei ;
Tang, Bo ;
Wu, Lizhu ;
Tung, Chenho .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (36) :17854-17859
[9]   Dynamic organization of inorganic nanoparticles into periodic micrometer-scale patterns [J].
Giraldo, O ;
Durand, JP ;
Ramanan, H ;
Laubernds, K ;
Suib, SL ;
Tsapatsis, M ;
Brock, SL ;
Marquez, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (25) :2905-2909
[10]  
Giraldo O., 2003, ANGEW CHEM, V115, P3011