Structural and optical properties of hydrogenated nanocrystalline silicon (nc-Si:H) films have been carefully studied as a function of hydrogen dilution of silane (R-H). Raman spectroscopic analysis showed that with increase in RH, the crystalline fraction in the films increases whereas crystallite size remains almost constant (similar to 8.7 nm). Also, the Raman spectra shows a blue shift of transverse optic (TO) phonon mode indicating that the films are stressed and the induced stress is compressive. The FTIR spectroscopic analysis revealed that the hydrogen predominantly incorporated in Si-H-2 and (Si-H-2)(n) bonding configuration. We have obtained high band gap (1.88-2.07 eV) at low hydrogen content (<2.5 at. %) over the entire range of R-H studied at reasonably high deposition rate (7.4-9.5 angstrom/s).
机构:
Indian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, IndiaIndian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, India
Bhattacharya, Koyel
;
Das, Debajyoti
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Indian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, IndiaIndian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, India
机构:
Indian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, IndiaIndian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, India
Bhattacharya, Koyel
;
Das, Debajyoti
论文数: 0引用数: 0
h-index: 0
机构:
Indian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, IndiaIndian Assoc Cultivat Sci, Energy Res Unit, Nano Sci Grp, Kolkata 700032, W Bengal, India